The apparent inner calm of quantum materials
Transitions between different phases of matter are part of our day-to-day lives: when water freezes, for example, it passes from liquid to solid state. Some of these transitions may be of a different kind, resulting from so-called topological excitations that force all the particles to act in unison. Researchers from the University of Geneva (UNIGE) and the CEA,CNRS and UGA have been studying BACOVO - a one-dimensional quantum material unknown to the general public - in collaboration with scientists from the neutronic centers ILL and PSI. They have discovered in this material a novel topological phase transition, governed not by a single type of topological excitation, but by two different ones. In addition, they were able to choose which of the two sets would dominate the other.
The helix structure of BACOVO: the oxygen atoms, represented in red, are organized in octahedra around the cobalt atoms, located at their center. The blue arrows represent the small moments carried by the cobalt atoms, ordered antiferromagnetically along the helical chain.
© CEA/CNRS/UGA
The researchers drew on the work of the 2016 Nobel Prize for physics awarded to David Thouless, Duncan Haldane, and Michael Kosterlitz. The three physicists predicted that a set of topological excitations in a quantum material is likely to induce a phase transition. Numerous theories have been developed about these topological excitations, including the feasibility of combining two of them in a single material. But is that a real possibility? And if so, what would happen? The teams from UNIGE and CEA, CNRS and UGA were able to provide the first experimental confirmation of the theory predicting the existence of two simultaneous sets of topological excitations and the competition between them. All in all, it is a small revolution in the mysterious world of quantum properties.
Theory and experimentation intimately linked
The researchers from CEA, CNRS, and Université Grenoble Alpes were working on a one-dimensional antiferromagnetic material with particular properties: BACOVO (BaCo2V2O8). "We performed various experiments on BACOVO, an oxide characterised by its helical structure," underline Béatrice Grenier, Sylvain Petit and Virginie Simonet, researchers at the CEA, CNRS and UGA. "But our experimental results evidenced a puzzling phase transition" - which is why their team called on Thierry Giamarchi, a professor in the Department of Quantum Matter Physics in UNIGE's Faculty of Science. The Geneva physicist explains: "Based on their results, we established theoretical frameworks capable of interpreting them. These theoretical models were then tested again using new experiments so they could be validated."
Creating the "standard model"
The aim was to understand how BACOVO's quantum properties act, especially their topological excitations. "For this purpose, we used neutron scattering, meaning we sent a neutron beam onto the material. The neutrons behave like small magnets that interact with those of BACOVO, according to a strategy "disturb in order to reveal", helping us to understand their properties," says Quentin Faure, Ph-D student at the Institute for Nanoscience and Cryogenics (CEA/UGA) and Néel Institute. When the model developed at UNIGE matches the experiment, it becomes the material's "standard model". Professor Giamarchi enthusiastically points out: "And, in fact, the model we established with Shintaro Takayoshi predicted exactly the outcome seen in the experiment!"
A material with unexpected properties
But this experiment also led to a discovery that the scientists had not anticipated. "After settling on the "standard model" for BACOVO, we observed unexpected properties,» says Shintaro Takayoshi, researcher in the Department of Quantum Matter Physics in UNIGE's Faculty of Science. When placed in a magnetic field, BACOVO develops a second set of topological excitations that are in competition with the first one, confirming theories from the 1970s and 1980s organised around the field opened up by the work of the Nobel scientists. "As well as proving the existence of this confrontation between two sets of topological excitations within the same material - an unprecedented event - we were able to experimentally control which set would dominate the other", adds the Genevan researcher. And that is a first!
What was originally a theoretical hypothesis became a verified experiment. The in-depth analysis of BACOVO undertaken by the physicists proved that two sets of topological excitations come into direct confrontation in the same material and control the state of matter, which differs according to the dominant set, yielding a quantum phase transition. Furthermore, the scientists succeeded in controlling which set prevails, meaning they could adjust BACOVO's state of matter at will. "These results open up a whole range of possibilities in terms of quantum physics research," concludes Professor Giamarchi. "It's true that we are still at the fundamental level, but it's through this kind of discovery that we are getting closer every day to applications for the quantum properties of materials... and why not quantum computers!?"
Original publication
Quentin Faure, Shintaro Takayoshi, Sylvain Petit, Virginie Simonet, Stéphane Raymond, Louis-Pierre Regnault, Martin Boehm, Jonathan S. White, Martin Månsson, Christian Rüegg, Pascal Lejay, Benjamin Canals, Thomas Lorenz, Shunsuke C. Furuya, Thierry Giamarchi & Béatrice Grenier; "Topological quantum phase transition in the Ising-like antiferromagnetic spin chain BaCo2V2O8"; Nature Physics; 2018
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