One-nanometer trimetallic alloy particles created
Overview
The research group led by Kimihisa Yamamoto of Tokyo institute of Technology developed a method of synthesizing microscopic alloy nanoparticles using branched molecules "dendrimers" they themselves had developed in Yamamoto Atom Hybrid Project on the ERATO program, the Exploratory Research for Advanced Technology, research funding program supported by Japan Science and Technology Agency (JST). Molecules called dendrimers have a regular branching structure with only one definite molecular weight although they are classified as macromolecules. The research group implemented many coordination sites for forming metal ions and complexes. By using a dendrimer with such coordination sites as a template for the nanoparticle, the group was able to synthesize a nanoparticle with a controlled number of atoms.
Further, they evaluated the activity of this alloy nanoparticle as an oxidization catalyst for hydrocarbons under ordinary pressures when using oxygen in the air as the oxidizing agent, and found that its activity was 24 times greater than that of commercially available catalysts for oxidization of organic compounds. They also found that, by adding a catalytic amount of organic hydroperoxide, this catalyst promotes the oxidization of hydrocarbon into aldehydes and ketones under ordinary temperatures and pressures. Further, by comparing the changes in activity due to alloy catalysts of different metallic compositions and examining the composition and other characteristics of the intermediates, ketones and organic hydroperoxides, the group was able to observe the process of reaction promotion due to the alloying of the catalyst.
Future Development
The catalytic transformation of inactive hydrocarbons to substances with higher added value is a technology garnering much attention in recent times.?The knowledge gained from this research is anticipated to become a design guideline for new high-performance catalysts. The method for synthesizing alloy nanoparticles developed in this research can be used generally and applied to other metals. For this reason, this could be said to be the technology uncovering the reactivity of other microscopic alloy nanoparticles, whose catalytic performance had not been known. Further study is required on the increase of catalytic activity at the interface of copper and other noble metals in the oxidizing transformations of other organic compounds, not only the oxidization of hydrocarbons. Application is anticipated for next-generation high-performance materials in the fields as diverse as optics, electronics, and energy.
Original publication
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