New properties of uranium compounds

17-Oct-2018 - Russian Federation

Scientists from Russia, China, and the United States predicted and experimentally identified new uranium hydrides, predicting superconductivity for some of them.

Of particular interest to scientists are the so-called "high-temperature superconductors" that boast superconductivity at less extreme temperatures. The highest temperature superconductors are known to date and widely used in electronics operate at -183° C (while the record of high-temperature superconductivity, established in 1993, was -138 °C) and, therefore, need to be constantly cooled. In 2015, a rare sulfur hydride (H3S) set a new high-temperature superconductivity record of -70 °C , although at pressures as high as 1,500,000 atm.

A group of physicists led by Professor of Skoltech and Moscow Institute of Physics and Technology (MIPT) Artem R. Oganov predicted that much lower pressures of about 50,000 atm can produce 14 new uranium hydrides, of which only one, UH3, has been known to date. They include compounds rich in hydrogens, such as UH7 and UH8, that the scientists predicted to be superconducting too. Many of these compounds were then obtained in the experiments conducted by the teams of Professor Alexander Goncharov at the US Carnegie Institution of Washington (USA) and the Institute of Solid State Physics of the Chinese Academy of Sciences. The calculations suggest that the highest-temperature superconductor is UH7 which displays superconducting capability at -219° C - a temperature level that can be increased further by doping.

"After H3S was discovered, scientists started eagerly searching for superconducting hydrides in other non-metals, such as selenium, phosphorus, etc. Our study showed that metal hydrides hold as much potential as non-metals in terms of high-temperature superconductivity," says the main author of the study Ivan Kruglov, a researcher in Computational Materials Discovery Laboratory at MIPT.

"The two highlights of our results are that high pressure produces an amazingly rich collection of hydrides, most of which do not fit into classical chemistry, and that these hydrides can actually be obtained and become superconducting at very low pressures, perhaps even at atmospheric pressure," says Artem Oganov.

Original publication

Kruglov, Ivan A. and Kvashnin, Alexander G. and Goncharov, Alexander F. and Oganov, Artem R. and Lobanov, Sergey S. and Holtgrewe, Nicholas and Jiang, Shuqing and Prakapenka, Vitali B. and Greenberg, Eran and Yanilkin, Alexey V.; "Uranium polyhydrides at moderate pressures: Prediction, synthesis, and expected superconductivity"; Science Advances; 2018

https://www.chemeurope.com/en/news/161869/new-properties-of-uranium-compounds.html