Silk could be new 'green' material for next-generation batteries

13-Apr-2015 - USA

lithium-ion batteries have enabled many of today's electronics, from portable gadgets to electric cars. But much to the frustration of consumers, none of these batteries last long without a recharge. Now scientists report in the journal ACS Nano the development of a new, "green" way to boost the performance of these batteries — with a material derived from silk.

Chuanbao Cao and colleagues note that carbon is a key component in commercial Li-ion energy storage devices including batteries and supercapacitors. Most commonly, graphite fills that role, but it has a limited energy capacity. To improve the energy storage, manufacturers are looking for an alternative material to replace graphite. Cao's team wanted to see if they could develop such a material using a sustainable source.

The researchers found a way to process natural silk to create carbon-based nanosheets that could potentially be used in energy storage devices. Their material stores five times more lithium than graphite can — a capacity that is critical to improving battery performance. It also worked for over 10,000 cycles with only a 9 percent loss in stability. The researchers successfully incorporated their material in prototype batteries and supercapacitors in a one-step method that could easily be scaled up, the researchers note.

Original publication

"Hierarchical Porous Nitrogen-Doped Carbon Nanosheets Derived from Silk for Ultrahigh-Capacity Battery Anodes and Supercapacitors."; ACS Nano 2015.

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