Molecules as circuits
The Kondo effect can improve a molecule's conductivity
The Kondo effect, first described last century by the Japanese physicist Jun Kondo, is observed when magnetic impurities, i.e., very few atoms (even only 1 in 1000) of magnetic material such as iron are added to metals like gold or copper. Even molecules like nitric oxide behave like magnetic impurities: when located between metal electrodes they give rise to a Kondo effect. This effect, as the study authors show, could be exploited to change the conductance between the two electrodes. Requist and Tosatti created a computer model of the Kondo effect under these conditions and formulated predictions on the behaviour of the molecules. These were then tested in experiments carried out by the experimental physicists involved in the study.
The results are encouraging: "Our work demonstrates for the first time that we can predict the Kondo effect quantitatively and it offers a theoretical basis for similar calculations with larger and more complex molecules. In the future it might be helpful when searching for the most appropriate molecules for these purposes", commented Requist.
More in detail…
The Kondo effect occurs when the presence of a magnetic atom (an impurity) causes the movement of electrons in a material to behave in a peculiar way.
"Every electron has a mechanical or magnetic rotation moment, termed spin", explains Erio Tosatti. "Kondo is a phenomenon related to the spin of metal electrons when they encounter a magnetic impurity. The free metal electrons cluster around the impurity and "screen it out" so that it can no longer be detected, at least so long as the temperature is sufficiently low". This results in specific properties of the material, for example an increase in electrical resistance. "Conversely, in conditions involving very small size scales (the tip of a tunnelling electron microscope) such as those used in this study, the result is instead an increase in conductivity", explains Requist.
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