Methane emissions from landfill could be turned into sustainable jet fuel in plasma chemistry leap
New research could help create a circular economy for waste-generated greenhouse gas emissions
Luisa Low, University of Sydney
Professor PJ Cullen, Dr Tianqi Zhang and Dr Emma Lovell
Methane is a far more potent greenhouse gas than carbon dioxide (CO2). According to the International Energy Agency, the concentration of methane in the atmosphere is currently around two-and-a-half times greater than pre-industrial levels and is increasing steadily, with waste emissions and the burning of fossil fuels accounting for a significant proportion.
The research was published in the Journal of the American Chemical Society.
Australia recently joined the international methane mitigation agreement with the United States, the European Union, Japan and the Republic of Korea.
Lead author, Professor PJ Cullen from the University of Sydney’s School of Chemical and Biomolecular Engineering and Net Zero Initiative said: “Globally, landfills are a major emitter of greenhouse gases, mainly a mixture of CO2 and methane. We have developed a process that would take these gases and convert them into fuels, targeting sectors that are difficult to electrify, like aviation.”
“Modern landfill facilities already capture, upgrade and combust their gas emissions for electricity generation, however, our process creates a much more environmentally impactful and commercially valuable product,” he said.
Global landfill emissions are estimated at 10–20 million tonnes of greenhouse gases per year, a value comparable to the emissions of the global energy sector.
Aviation currently accounts for approximately three percent of the world’s emissions. Creating a “closed loop” fuel based on existing emissions would eliminate the need for traditional and sustainable jet fuels, which add further emissions into the atmosphere.
How plasma makes the process work
The process would work by extracting methane from a landfill site, known as a methane well, which uses a shaft-like mechanism to extract gases.
“The beauty of this is that this simple process captures almost the exact composition that we need for our process,” said Professor Cullen.
“Non-thermal plasma is an electricity-driven technology which can excite gas at both a low temperature and atmospheric pressure. Essentially, what this means is this approach facilitates the conversion of the gas into value-added products by inducing plasma discharge within forming gas bubbles. The process doesn’t require heat or pressure, meaning it requires less energy, making it highly compatible with renewable energy power sources.”
Original publication
Josip Knezevic, Tianqi Zhang, Renwu Zhou, Jungmi Hong, Rusen Zhou, Christopher Barnett, Qiang Song, Yuting Gao, Wanping Xu, Dingxin Liu, Nicholas Proschogo, Biswaranjan Mohanty, Jyah Strachan, Behdad Soltani, Fengwang Li, Thomas Maschmeyer, Emma C. Lovell, Patrick J. Cullen; "Long-Chain Hydrocarbons from Nonthermal Plasma-Driven Biogas Upcycling"; Journal of the American Chemical Society, 2024-4-30