Using clay to combat eternal toxins

TU Freiberg clarifies basis for innovative PFAS filter made of clay

06-Dec-2023

Prof. Martin Bertau (left) and doctoral student Paul Scapan in the lab.

TU Bergakademie Freiberg / Andreas Hiekel

PFAS filters available for industrial waste are usually made of activated carbon (PFAS = perfluorinated and polyfluorinated alkyl compounds). As this is comparatively expensive, researchers are looking for alternative filter materials for the so-called "eternal toxins", whose hazardous residues only degrade very slowly in the environment. A team from the TU Bergakademie Freiberg is now proposing a clay made of bentonite modified with organic substances as a possible PFAS filter. The results appear in the current issue of the journal "Chemie Ingenieur Technik".

In laboratory tests, the team led by chemistry professor Martin Bertau achieved a filter performance of up to 95 per cent of perfluoroheptanoic acid (PFHpA) with the innovative material. PFHpA is a prominent representative of PFAS and is frequently detected in environmental analyses. "The so-called organoclays are known for their good filter effect. We have now investigated the modification of the material with the help of organic additives that are specialised in "capturing" the PFAS," explains Prof. Martin Bertau.

The chemists can insert organic additives between the split clay layers in the laboratory like in a stack of cards. "The organic components peek out of the clay components in such a way that the carbon atoms can interact with the PFAS," explains Paul Scapan, who is investigating the clay filters for his doctoral thesis. "These carbon atoms have the ability to grab the PFAS molecules and bind them." The organoclay with the bound PFAS can then be incinerated at a temperature of at least 1,200 degrees, completely destroying the pollutants.

Environmentally friendly and recyclable

Doctoral researcher Paul Scapan is now investigating which readily biodegradable molecules can best fulfil the gripper function for the various PFAS. If the additives are environmentally friendly, the ashed clay filter can be completely reused. "The material is suitable for further processing into geopolymers as an environmentally friendly cement alternative, for example," says Prof Martin Bertau.

What other advantages the organoclays could have

With the various additives, the filter effect of the innovative organoclays can be specifically tailored to numerous perfluorinated and polyfluorinated alkyl compounds. "Compared to filters made of activated carbon currently available on the market, the organoclays would be around a tenth of the cost in terms of PFAS elimination performance, according to our current state of knowledge," calculates Paul Scapan.

Background: Where PFAS are used

PFAS stands for per- and polyfluorinated alkyl substances. In industrially produced organic compounds, hydrogen atoms are replaced by fluorine atoms. This makes them extremely resistant. More than 10,000 solid, liquid and gaseous chemicals are PFAS, some of which are carcinogenic and harmful to health. They are used, for example, in impregnation sprays, functional clothing, medical products and non-stick coatings.

Hazardous PFAS residues are detected in the environment all over the world and accumulate in water, soil, plants and animals. PFAS can even be found in the polar regions - and in the blood of children. Even with a planned future ban on PFAS in the EU, these substances have already been released into the environment and only degrade very slowly. A ban on all PFAS is now being discussed and is currently being drafted by the European Chemicals Agency (ECHA).

Original publication

Paul Scapan, Jannis Hassler, Christoph Piribauer, Sandra Pavón, Ines Aubel, Jan Werner, Martin Bertau; "Organo‐Pillared‐Clay: Synthesis, Characterization, and Applications for Treatment of Perfluoroalkyl Substances"; Chemie Ingenieur Technik, Volume 95, 2023-10-24

https://www.chemeurope.com/en/news/1182201/using-clay-to-combat-eternal-toxins.html