New superacid: Substance converts harmful compounds into sustainable chemicals

Discovery could convert non-biodegradable fluorinated hydrocarbons and, in perspective, even climate-damaging greenhouse gases

28-Feb-2023 - Germany

Researchers at Paderborn University have succeeded in producing very special catalysts, known as “Lewis superacids”, which can be used to break strong chemical bonds and speed up reactions. The production of these substances has, until now, proven extremely difficult. The chemists’ discovery enables non-biodegradable fluorinated hydrocarbons, similar to Teflon, and possibly even climate-damaging greenhouse gases, such as sulphur hexafluoride, to be converted back into sustainable chemicals. The researchers have now published their results in renowned journal “Angewandte Chemie” (Applied Chemistry).

“Lewis acids” are compounds that add electron pairs. Because of this ability, they are often used to speed up chemical reactions. Lewis superacids are stronger than antimony pentafluoride – the strongest Lewis acid – and can break even the toughest bonds. Professor Jan Paradies from the Department of Chemistry at Paderborn University explains: “For strong bonds, you need highly reactive reagents, i.e. substances that are extremely reactive.” The new catalyst can split, for example, carbon-fluorine or sulphur-fluorine bonds, which are particularly robust. “Intrinsically, these Lewis superacids are incredibly reactive, which makes them difficult to produce and use. Using a trick, we managed to produce such molecules and use them in catalytic reactions. This makes it possible to, for example, activate and further convert virtually inert, i.e. less reactive, carbon-fluorine or sulphur-fluorine bonds,” says Paradies.

The researchers in the Department of Chemistry have joined forces in the Center for Sustainable Systems Design (CSSD), which bundles interdisciplinary basic research in the field of sustainability at Paderborn University. The complementary scientific interests of the groups involved form the nucleus for new approaches in the development of sustainable systems. The centre wants to leverage this capacity to contribute to the sustainable use of resources. This and related topics are also covered in Paderborn within the framework of its “Sustainable Chemistry” master’s programme. Paradies: “We’re thereby placing a clear emphasis on sustainability not only in research, but also in teaching.”