Success in synthesizing biodegradable plastic materials using sunlight and CO₂

80% yield!

12-Oct-2022 - Japan

Tremendous effort has been put into making plastics not only durable and convenient but also environmentally-friendly materials for everyday products. Osaka Metropolitan University scientists made a significant advance in this journey with their innovative artificial photosynthesis technology that produces biodegradable plastics from acetone and CO₂, addressing the plastic waste crisis while moving toward the goal of carbon neutrality. Their findings were published in Chemical Communications.

The research team led by Professor Yutaka Amao from the Research Center for Artificial Photosynthesis at Osaka Metropolitan University has successfully synthesized 3-hydroxybutyrate, a raw material for poly-3-hydroxybutyrate (PHB)—a strong water-insoluble polyester used for packaging materials—from acetone and CO₂. With a visible light-driven catalytic system utilizing sunlight and two biocatalysts, the researchers achieved a yield of about 80%.

Mimicking natural photosynthesis, the team artificially reproduced a light reaction, which involves sunlight, and a dark reaction, which fixes CO₂, and synthesized 3-hydroxybutyrate.

This study is the latest in a series of the researchers’ articles on using artificial photosynthesis to produce useful substances, generate renewable energy, and achieve a carbon neutral society. “This research result of synthesizing 3-hydroxybutyrate, a raw material for PHB, from CO₂ is a significant contribution to addressing both the plastic and CO₂ reduction issues,” said Professor Amao. “In the future, we aim to produce 3-hydroxybutyrate through artificial photosynthesis using CO₂ contained in exhaust gas emitted from factories.”

Original publication

Yu Kita and Yutaka Amao; Visible-light driven 3-hydroxybutyrate synthesis from CO2 and acetone with the hybrid system of photocatalytic NADH regeneration and multi-biocatalysts; Chemical Communications; 2022

https://www.chemeurope.com/en/news/1178048/success-in-synthesizing-biodegradable-plastic-materials-using-sunlight-and-co.html