Two-dimensional ionic liquids to effectively capture carbon dioxide

14-Jul-2022 - China

In the context of global concern about climate change and greenhouse gas control, a new technology for CO₂ capture, utilization, and storage has attracted broad attention.

Ionic liquids, composed of only cations and anions, are considered a new type of CO₂ adsorbent due to their ultralow vapor pressure and environmentally friendly features.

Recently, a group led by Profs ZHANG Suojiang and HE Hongyan from the Institute of Process Engineering (IPE) of the Chinese Academy of Sciences (CAS) has found that two-dimensional ionic liquids show a completely different melting behaviour than the bulk phase, leading to a high CO₂ adsorption capacity and structural robustness during the CO₂ adsorption-desorption process.

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This study was published in Cell Reports Physical Science on July 12.

The researchers found that ionic liquids can form a two-dimensional-monolayer, ordered, checkerboard structure when supported by a metal surface. The two-dimensional ionic liquids exhibited anomalous stepwise melting processes, involving localized-rotated, out-of-plane-flipped, and fully disordered states, rather than the single melting point for the bulk ionic liquids.

"Anions and cations are arranged together in a checkerboard manner, thus forming a two-dimensional, ordered Z-bond network. This makes it more likely for the multi-step melting behaviors such as ionic rotation and flip," said Prof. HE.

The massive molecular dynamics simulation indicates that the two-dimensional ionic liquids show excellent performance for CO₂ capture due to the unsaturated and exposed Z-bonds. The mole fraction of CO₂ adsorbed by two-dimensional [Mmim]PF₆ was improved by at least one order of magnitude compared with the corresponding bulk ionic liquids.

"The higher CO₂ adsorption capability suggests that such two-dimensional ionic liquids could serve as functional layers of the catalyst to enhance the mass transfer process of CO₂, which is important for the fixation and conversion of CO₂," said Associate Professor WANG Yanlei of IPE.

This two-dimensional editing technique for ionic liquids is expected to provide a new method for the precise control and functional design of liquids, which is promising for various chemical engineering applications involving solvents, electrolytes, and liquid catalysts.

Original publication

Yanlei Wang et al.; Two-dimensional ionic liquids with an anomalous stepwise melting process and ultrahigh CO2 adsorption capacity; Cell Reports Physical Science; 2022

https://www.chemeurope.com/en/news/1176896/two-dimensional-ionic-liquids-to-effectively-capture-carbon-dioxide.html

Original publication

Yanlei Wang et al.; Two-dimensional ionic liquids with an anomalous stepwise melting process and ultrahigh CO2 adsorption capacity; Cell Reports Physical Science; 2022

Topics

carbon capture ionic liquids carbon dioxide CO2 capturing

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