Energy Conversion: Make carbonate not carbon dioxide

Scientists developed a technique to avoid CO2 in energy conversion processes with carbon-containing fuels

19-Nov-2021 - Germany

Nature knows several ways how to capture carbon dioxide (CO₂). The most prominent one is photosynthesis, where sun light is used to fix CO₂ into biomass. Nowadays, research groups around the world try hard to mimic this process and to realize artificial photosynthesis. The ultimate goal is to efficiently ‘photo-transform’ CO₂ into synthetic fuels. However, nature knows also other strategies for capturing carbon dioxide, such as dissolving CO₂ as carbonate (CO₃^2-) in the oceans. Shellfish then make use of the dissolved carbonate and build CaCO₃-based solid structures for shelter, which finally end up safely in rocks around the globe.

Inspired by the way shellfishes capture carbon dioxide, LMU scientists at the Nano-Institute Munich developed the vision to transform a carbon-containing fuel into a carbon-free fuel without releasing CO₂ but capture carbon as carbonate. They chose alkaline methanol and devised a light-triggered system, which efficiently produced hydrogen and carbonate in the form of tiny stones. They introduced a novel multi-layer device to make maximum use of the incident light and the catalysts.

Dr. Yiou Wang, who performed most of the experimental work is a Fellow of the Alexander-von-Humboldt foundation working at the Chair for Photonics and Optoelectronics led by Prof. Jochen Feldmann. He remembers: ‘I had two moments of great excitement: First when I saw the hydrogen bubbles emerging on the catalyst and second when I noticed the carbonate crystals precipitating from the solution.’ Dr. Jacek Stolarczyk, an expert in artificial photosynthesis, adds: ‘Light is an excellent means of triggering energy conversion reactions, more convenient to use than heat and pressure.’

A possible application is the in-situ production of required hydrogen from low-cost alcohols, which avoids the risks to store and transport hydrogen before use in fuel cells. Such a carbon-neutral and light-triggered process produces hydrogen safely and efficiently, which could enable scalable fabrication and hold promise for broad and practical applications. Prof. Jochen Feldmann states: ‘Avoiding CO₂-emission by binding the carbon in carbonates might generally become an important concept when using carbon-containing fuels.’

Original publication

Yiou Wang, E.-P. Yao, L. Wu, Jochen Feldmann, Jacek Stolarczyk; "A Multi-layer Device for Light-triggered Hydrogen Production from Alkaline Methanol"; Angewandte Chemie Int. Ed.; 2021

https://www.chemeurope.com/en/news/1173603/energy-conversion-make-carbonate-not-carbon-dioxide.html

Original publication

Yiou Wang, E.-P. Yao, L. Wu, Jochen Feldmann, Jacek Stolarczyk; "A Multi-layer Device for Light-triggered Hydrogen Production from Alkaline Methanol"; Angewandte Chemie Int. Ed.; 2021

Topics

carbon dioxide carbonates carbon hydrogen fuels

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Organizations

LMU