Proton transfer between titania surface and dye observed for photocatalysis evaluation
Reprinted with permission from J. Phys. Chem. C, 2021, 125, 40. 21803-22396 (Supplementary Cover). Copyright 2021 American Chemical Society.
Fluorescein, an organic dye sensitive to light and acidity/basicity was adsorbed on the surface of the titania as a probe molecule. The group used a time-resolved surface plasmon resonance (SPR) spectroscopy with a femtosecond pulsed laser. By using femtosecond pulsed laser SPR spectroscopy, the group was able to indirectly observe the proton transfer process from the dye to the titania surface and proved the formation of basic hydroxyl groups.
Observation through the UV irradiation time showed that the surface became more basic with OH groups on the surface of the titania which accepts the protons from the fluorescein monoanion. Time-resolved fluorescence probe observation using organic dyes that are sensitive to light and acidity/basicity is a very effective method for observing small light-induced behaviors (proton transfer processes) that occur on solid surfaces in a very short time.
The researchers were successful in observing the dianion and monoanion ratio of the fluorescein through the establishment of the SPR spectroscopy method. Professor Nishikiori hopes to continue to contribute to advances in hydrogen production with photocatalytic water splitting with the establishment of this simple method that enables researchers to observe and evaluate the activity of the photocatalysis.
Original publication
Other news from the department science
Most read news
More news from our other portals
See the theme worlds for related content
Topic World Spectroscopy
Investigation with spectroscopy gives us unique insights into the composition and structure of materials. From UV-Vis spectroscopy to infrared and Raman spectroscopy to fluorescence and atomic absorption spectroscopy, spectroscopy offers us a wide range of analytical techniques to precisely characterize substances. Immerse yourself in the fascinating world of spectroscopy!
Topic World Spectroscopy
Investigation with spectroscopy gives us unique insights into the composition and structure of materials. From UV-Vis spectroscopy to infrared and Raman spectroscopy to fluorescence and atomic absorption spectroscopy, spectroscopy offers us a wide range of analytical techniques to precisely characterize substances. Immerse yourself in the fascinating world of spectroscopy!