Industrial compound gets eco-friendly reaction
Scientists have found catalysts that improve an important industrial reaction and make it more eco-friendly
Nagoya University scientists have developed a chemical reaction that produces high yields of a compound used in a wide variety of industries, without needing high temperatures or toxic catalysts. The approach was described in the journal ACS Catalysis and offers a practical and sustainable solution for industrial (meth)acrylate (= acrylate or methacrylate) ester synthesis.
Sodium or magnesium aryloxides can catalyse the transesterification of methyl (meth)acrylate at room temperature, with high chemoselectivity, producing a high yield of (meth)acrylate ester, and without the use of toxic metals or ligands.
Kazuaki Ishihara
(Meth)acrylate esters are used in industrial coatings and masonry, and to make plastics, dyes and adhesives. But the chemical process for making them from methyl (meth)acrylates involves high temperatures, long reaction times and toxic compounds. It can also result in unwanted side reactions.
Scientists, including Nagoya University professor Kazuaki Ishihara and colleagues, have been working on improving this process to make it more eco-friendly. Specifically, they worked on improving the catalyst involved in the chemical reaction that turns methyl (meth)acrylates into (meth)acrylate esters, called transesterification.
"Millions of tons of (meth)acrylate esters are produced annually and are among the most important manufactured chemicals around," says Ishihara. "Their transesterification, using alcohol and a catalyst, fine-tunes their properties, producing a wide range of (meth)acrylate esters."
Ishihara and his colleagues found that sterically bulky sodium and magnesium aryloxides worked very well as non-toxic alternatives. They catalysed the transesterification of methyl (meth)acrylates at the relatively mild temperature of 25°C, producing high yields of a broad range of (meth)acrylate esters depending on the type of alcohol used in the reaction.
The team also conducted computational calculations to uncover the details of what happened during the chemical reaction, showing that it had high chemoselectivity; in other words, the reaction happened the way the scientists wanted it to without having undesirable side reactions.
"Our transesterification process is a practical and sustainable candidate for industrial (meth)acrylate ester synthesis, providing excellent chemoselectivity, high yields, mild reaction conditions and a lack of any toxic metal salts," says Ishihara.
The team next aims to collaborate with colleagues in industry to use their approach in (meth)acrylate ester production. They also aim to continue searching for efficient catalysts for the transesterification of methyl (meth)acrylates and to develop recyclable catalysts.
Original publication
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