Surprising discovery could lead to better batteries
A collaboration led by scientists at the U.S. Department of Energy's (DOE) Brookhaven National Laboratory has observed an unexpected phenomenon in lithium-ion batteries--the most common type of battery used to power cell phones and electric cars. As a model battery generated electric current, the scientists witnessed the concentration of lithium inside individual nanoparticles reverse at a certain point, instead of constantly increasing. This discovery is a major step toward improving the battery life of consumer electronics.
2D maps depict the concentration of lithium inside a single nanoparticle. Over time, the concentration increases, decreases, and then increases again.
Brookhaven National Laboratory
"If you have a cell phone, you likely need to charge its battery every day, due to the limited capacity of the battery's electrodes," said Esther Takeuchi, a SUNY distinguished professor at Stony Brook University and a chief scientist in the Energy Sciences Directorate at Brookhaven Lab. "The findings in this study could help develop batteries that charge faster and last longer."
Visualizing batteries on the nanoscale
Inside every lithium-ion battery are particles whose atoms are arranged in a lattice--a periodic structure with gaps between the atoms. When a lithium-ion battery supplies electricity, lithium ions flow into empty sites in the atomic lattice.
"Previously, scientists assumed that the concentration of lithium would continuously increase in the lattice," said Wei Zhang, a scientist at Brookhaven's Sustainable Energy Technologies Department. "But now, we have seen that this may not be true when the battery's electrodes are made from nano-sized particles. We observed the lithium concentration within local regions of nanoparticles go up, and then down--it reversed."
Electrodes are often made from nanoparticles in order to increase a battery's power density. But scientists have not been able to fully understand how these electrodes function, due to a limited ability to watch them work in action. Now, with a unique combination of experimental tools, the scientists were able to image reactions inside the electrodes in real time.
Similar to how a sponge soaks up water, we can see the overall level of lithium continuously increase inside the nano-sized particles," said Feng Wang, the leader of this study and a scientist in Brookhaven's Sustainable Energy Technologies Department. "But unlike water, lithium may preferentially move out of some areas, creating inconsistent levels of lithium across the lattice."
The scientists explained that uneven movement of lithium could have lasting, damaging effects because it strains the structure of the active materials in batteries and can lead to fatigue failure.
"Before lithium enters the lattice, its structure is very uniform," Wang said. "But once lithium goes in, it stretches the lattice, and when lithium goes out, the lattice shrinks. So each time you charge and drain a battery, its active component will be stressed, and its quality will degrade over time. Therefore, it is important to characterize and understand how lithium concentration changes both in space and time."
Combining tools of the trade
In order to make these observations, the scientists combined transmission electron microscopy (TEM) experiments--conducted at the Center for Functional Nanomaterials (CFN), a DOE Office of Science User Facility at Brookhaven Lab, and at Brookhaven's Condensed Matter Physics and Materials Science Department--with x-ray analyses at the National Synchrotron Light Source (NSLS), a DOE Office of Science user facility at Brookhaven that closed in 2014 when its successor, NSLS-II, opened.
"Wang's team combined TEM with x-ray techniques," said Yimei Zhu, co-author of the study and a senior physicist at Brookhaven Lab. "Both methods use a similar approach to analyze the structure of materials, but can provide complementary information. Electrons are sensitive to the local structure, while x-rays can probe a larger volume and enable much better statistics."
The Brookhaven team also developed a nanoscale model battery that could mimic the function of lithium-ion batteries that would "fit" into a TEM. Computer simulations conducted at the University of Michigan further confirmed the surprising conclusions.
"We initially thought that the reversal mechanism was similar to those previously proposed, which stemmed from the interactions between nearby particles," said Katsuyo Thornton, a professor of materials science and engineering at the University of Michigan, Ann Arbor, who led the theoretical effort. "However, it turned out a concentration reversal within a single particle could not be explained by existing theories, but rather, it arises from a different mechanism. Simulations were critical in this work because, without them, we would have made an incorrect conclusion."
While the study focused on lithium-ion batteries, the scientists say the observed phenomenon may also occur in other high-performance battery chemistries.
"Down the road, we plan to use the world-class facilities at CFN and NSLS-II to more closely examine how battery materials work, and to find solutions for building new batteries that can charge faster and last longer," Wang said. "These facilities offer the ideal tools for imaging the structure of battery materials in real time and under real-world conditions."
Original publication
Zhang, Wei and Yu, Hui-Chia and Wu, Lijun and Liu, Hao and Abdellahi, Aziz and Qiu, Bao and Bai, Jianming and Orvananos, Bernardo and Strobridge, Fiona C. and Zhou, Xufeng and Liu, Zhaoping and Ceder, Gerbrand and Zhu, Yimei and Thornton, Katsuyo and Grey, Clare P. and Wang, Feng; "Localized concentration reversal of lithium during intercalation into nanoparticles"; Science Advances; 2018
Other news from the department science
![[Fe]-hydrogenase catalysis visualized using para-hydrogen-enhanced nuclear magnetic resonance spectroscopy](https://img.chemie.de/Portal/News/675fd46b9b54f_sBuG8s4sS.png?tr=w-712,h-534,cm-extract,x-0,y-16:n-xl)
These products might interest you
NANOPHOX CS by Sympatec
Particle size analysis in the nano range: Analyzing high concentrations with ease
Reliable results without time-consuming sample preparation
Eclipse by Wyatt Technology
FFF-MALS system for separation and characterization of macromolecules and nanoparticles
The latest and most innovative FFF system designed for highest usability, robustness and data quality
DynaPro Plate Reader III by Wyatt Technology
Screening of biopharmaceuticals and proteins with high-throughput dynamic light scattering (DLS)
Efficiently characterize your sample quality and stability from lead discovery to quality control
Get the chemical industry in your inbox
From now on, don't miss a thing: Our newsletter for the chemical industry, analytics, lab technology and process engineering brings you up to date every Tuesday and Thursday. The latest industry news, product highlights and innovations - compact and easy to understand in your inbox. Researched by us so you don't have to.
Most read news
More news from our other portals
See the theme worlds for related content
Topic World Battery Technology
The topic world Battery Technology combines relevant knowledge in a unique way. Here you will find everything about suppliers and their products, webinars, white papers, catalogs and brochures.
Topic World Battery Technology
The topic world Battery Technology combines relevant knowledge in a unique way. Here you will find everything about suppliers and their products, webinars, white papers, catalogs and brochures.
