Setting out to discover new, long-lived elements

For the first time, 'ion traps' were used to measure super heavy elements

15-Feb-2010 - Germany

Besides the 92 elements that occur naturally, scientists were able to create 20 additional chemical elements, six of which were discovered at the GSI Helmholtz Centre for Heavy Ion Research in Darmstadt. These new elements were produced artificially with particle accelerators and are all very short-lived: they decay in a matter of a split second. However, scientists predict the existence of even heavier elements with an extreme longevity, leaving them to only decay after years. These elements form an island of stability. Scientists at the GSI Helmholtz Centre for Heavy Ion Research in Darmstadt have developed and applied a measuring apparatus that might allow them to discover such long-lived elements.

An international team of scientists headed by Michael Block was able to trap atoms of the element 102, nobelium, in an ion trap. This is the first time in history that a so-called super heavy element had been trapped. Trapping the element allowed the research team to measure the atomic mass of Nobelium with unprecedented accuracy. The atomic mass is one of the most essential characteristics of an atom. It is used to calculate the atom's binding energy, which is what keeps the atom together. The atom's binding energy determines the stability of an atom. With the help of the new measuring apparatus, scientists will be able to identify long-lived elements on the so called islands of stability that can no longer be assigned by their radioactive decay . The island of stability is predicted to be located in the vicinity of the elements 114 to 120.

„Precisely measuring the mass of nobelium with our Shiptrap device was a successful first step. Now, our goal is to improve the measuring apparatus so that we can extend our method to heavier and heavier elements and, one day, may reach the island of stability", says Michael Block, head of the research team at the GSI Helmholtz Centre.

For their measurements, Michael Block and his team built a highly complex apparatus, the ion trap "Shiptrap", and combined it with "Ship", the velocity filter which was already used in the discovery of six short-lived elements at GSI. To produce nobelium, the research team used the GSI accelerator to fire calcium ions onto a lead foil. With the help of Ship, they then separated the freshly produced nobelium from the projectile atoms. Inside the Shiptrap apparatus, the nobelium was first decelerated in a gas-filled cell, then the slow ions were trapped in a so-called Penning trap.

Held inside the trap by electric and magnetic fields, the nobelium ion spun on a minuscule spiral course at a specific frequency. This frequency was used to calculate the atomic mass. With an uncertainty of merely 0,000005 per cent, this new technique allows determining the atomic mass and binding energy with unprecedented precision and, for the first time, directly without the help of theoretical assumptions.

Original publication: M. Block et al.; "Direct mass measurements above uranium bridge the gap to the island of stability"; Nature 2010, 463, 785-788

https://www.chemeurope.com/en/news/113423/setting-out-to-discover-new-long-lived-elements.html