Gas storage hots up!
Chemists in Canada have synthesised an amine functionalised metal organic framework that shows a preference for CO2 adsorption
The heat of adsorption – the amount of heat evolved during an adsorption, is a measure of the affinity of a gas for a material. Therefore, the higher the heat of adsorption of a gas, the better the gas capture and storage capability of the material.
In industry, amines are commonly used as scrubbers for CO2. Therefore, Shimizu’s aim was to develop a material with amine groups lining the pores. ‘In these materials, the size, shape and chemical functionalisation all contribute to the high affinity over the range of gas loading,’ says Shimizu.
In the future Shimizu and his team hope to develop crystalline MOF sorbents with larger pores and higher loadings. The high heat of adsorption seen in this research is a promising step forward. Shimizu believes that gas separations based on selective sorption, brings the ultimate goals much closer.
Original publication: G. K. H. Shimizu et. al., Chem. Commun., 2009
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