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Vanadium(III) bromide
Vanadium(III) bromide, also known as vanadium tribromide, is VBr3. In the solid-state, this species is a polymeric with octahedral vanadium(III) surrounded by six bromide ligands. Additional recommended knowledgeVBr3has been prepared by treatment of VCl4 with HBr: The reaction proceeds via the unstable vanadium(IV) bromide, VBr4, which releases Br2 at room temperature.[1] Like VCl3, VBr3 forms red-brown soluble complexes with dimethoxyethane and THF, such as mer-VBr3(THF)3.[2] Aqueous solutions prepared from VBr3 contain the salt trans-[VBr2(H2O)4]+. Evaporation of these solutions give the salt trans-[VBr2(H2O)4]Br.[3] References
Further reading
Categories: Bromides | Metal halides | Vanadium compounds |
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This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Vanadium(III)_bromide". A list of authors is available in Wikipedia. |