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Triethyl phosphite
Additional recommended knowledgeTriethylphosphite is prepared by treating phosphorus trichloride with ethanol in the presence of a base, typically a tertiary amine:[1]
Of the many related compounds can be prepared similarly, triisopropyl phosphite is an example (b.p. 43.5 °C/1.0 mm; CAS# 116-17-6). As a ligandIn coordination chemistry and homogeneous catalysis]], triethylphosphite finds use as a soft ligand. Its complexes are generally lipophilic and feature metals in low oxidation states. Examples include the colorless complexes FeH2(P(OEt)3)4 and Ni(P(OEt)3)4 (m.p. 187 °C).[2] References
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This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Triethyl_phosphite". A list of authors is available in Wikipedia. |