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Sodium maleonitriledithiolate
Sodium maleonitriledithiolate is the chemical compound described by the formula Na2S2C2(CN)2. The name refers to the cis compound, formally derived from maleonitrile. The dianion is a "dithiolene", i.e. a chelating alkene-1,2-dithiolate that serves as a non-innocent ligand for transition metals. Several complexes are known, such as [Ni(mnt)2]2-. Additional recommended knowledgeThe salt is synthesized by treating carbon disulfide with sodium cyanide to give the cyanodithioformate salt, which eliminates elemental sulfur in aqueous solution:[1]
The compound was first described by Bähr and Schleitzer 1958.[2] References
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This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Sodium_maleonitriledithiolate". A list of authors is available in Wikipedia. |