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Rosenmund reductionThe Rosenmund reduction is a chemical reaction that reduces an acid halide to an aldehyde using hydrogen gas over palladium-on-carbon poisoned with barium sulfate.[1][2][3] The reaction was named after Karl Wilhelm Rosenmund. Additional recommended knowledgeThe catalyst must be poisoned because otherwise the catalyst is too active and will reduce the acid chloride to a primary alcohol. Diisobutylaluminium hydride (DIBALH) can also reduce acid chlorides to aldehydes. See also
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This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Rosenmund_reduction". A list of authors is available in Wikipedia. |