Nanomechanics

Nanomechanics is a branch of nanoscience studying fundamental mechanical (elastic, thermal and kinetic) properties of physical systems at the nanometer scale. Nanomechanics has emerged on the cross-road of classical mechanics, solid-state physics, statistical mechanics, materials science, and quantum chemistry. As an area of nanoscience, nanomechanics provides a scientific foundation of nanotechnology.

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Often, nanomechanics is viewed as a branch of nanotechnology, i.e., an applied area with a focus on the mechanical properties of engineered nanostructures and nanosystems (systems with nanoscale components of importance). Examples of the latter include nanoparticles, nanopowders, nanowires, nanorods, nanoribbons, nanotubes, including carbon nanotubes (CNT) and boron nanotubes (BNT); nanoshells, nanomebranes, nanocoatings, nanocomposite/nanostructured materials, nanofluids (fluids with dispersed nanoparticles); nanomotors, etc.

Some of the well-established fields of nanomechanics are: nanomaterials, nanotribology (friction, wear and contact mechanics at the nanoscale), nanoelectromechanical systems (NEMS), and nanofluidics.

As a fundamental science, nanomechanics is based on some empirical principles (basic observations), arising from the smallness of physical sizes of the subject of study or research. Examples include:

• Discreteness of the subject (subject size becomes comparable with the interatomic lengths)
• Plurality, though finiteness, of degrees of freedom in the subject
• Rise of thermal fluctuations
• Rise of configuration entropy
• Rise of quantum effects

These principles serve to provides a basic insight into novel mechanical properties of nanometer objects. Novelty is understood in the sense that these properties are not present in similar macroscale objects or much different from the properties of those (e.g., nanorods vs. usual macroscopic beam structures). In particular, smallness of the subject itself gives rise to various surface effects determined by higher surface-to-volume ratio of nanostructures, and thus affects mechanoenergetic and thermal properties (melting point, heat capacitance, etc.) of nanostructures. Discreteness serves a fundamental reason, for instance, for the dispersion of mechanical waves in solids, and some special behavior of basic elastomechanics solutions at small scales. Plurality of degrees of freedom and the rise of thermal fluctuations are the reasons for thermal tunneling of nanoparticles through potential barriers, as well as for the cross-diffusion of liquids and solids. Smallness and thermal fluctuations provide the basic reasons of the Brownian motion of nanoparticles. Increased importance of thermal fluctuations and configuration entropy at the nanoscale give rise to superelasticity, entropic elasticity, and other exotic types of elasticity of nanostructures. Aspects of configuration entropy are also of great interest in the context self-organization and cooperative behavior of open nanosystems.

Quantum effects determine forces of interaction between individual atoms in physical objects, which are introduced in nanomechanics by means of some averaged mathematical models called interatomic potentials.

Subsequent utilization of the interatomic potentials within the classical multibody dynamics provide deterministic mechanical models of nano structures and systems at the atomic scale/resolution. Numerical methods of solution of these models are called molecular dynamics (MD), and sometimes molecular mechanics (especially, in relation to statically equilibrated (still) models). Nondeterministic numerical approaches include Monte-Carlo, Kinetic More-Carlo (KMC), and other methods. Contemporary numerical tools include also also hybrid multiscale approaches allowing concurrent or sequential utilization of the atomistic scale methods (usually, MD) with the continuum (macro) scale methods (usually, FEM) within a single mathematical model. Development of these complex methods is a separate subject of applied mechanics research.

Quantum effects also determine novel electrical, optical and chemical properties of nanostructures, and therefore they find even greater attention in adjacent areas of nanoscience and nanotechnology, such as nanoelectronics, advanced energy systems, and nanobiotechnology.

References

1. Bhushan B (editor). Springer Handbook of Nanotechnology, 2nd edition. Springer, 2007.

1. Liu WK, Karpov EG, Park HS. Nano Mechanics and Materials: Theory, Multiscale Methods and Applications. Wiley, 2006.

1. Cleland AN. Foundations of Nanomechanics. Springer, 2003.