Biogas

Biogas typically refers to a gas produced by the biological breakdown of organic matter in the absence of oxygen. Biogas is comprised primarily of methane and carbon dioxide. Biogas originates from biogenic material and is a type of biofuel. Biogas is a product of the anaerobic digestion or fermentation of biodegradable materials such as manure or sewage, municipal waste, and energy crops.

The methane in biogas gives it the ability to be used as a fuel. The combustion of which releases energy. In developing countries biogas can be used as a low-cost fuel for cooking. It can also be utilised in modern waste management facilities where it can be used in gas engines to generate electricity. Biogas is a renewable fuel and electricity produced from it can be used to attract renwable energy subsidies in some parts of the world.

Additional recommended knowledge

Essential Laboratory Skills Guide

Safe Weighing Range Ensures Accurate Results

What is the Sensitivity of my Balance?

Production

Main articles: anaerobic digestion and landfill gas

  Depending on where it is produced, biogas can also be called swamp, marsh, landfill or digester gas. A biogas plant is the name often given to an anaerobic digester that treats farm wastes or energy crops.

Biogas can be produced utilising anaerobic digesters. These plants can be fed with energy crops such as maize silage or biodegradable wastes including sewage sludge and food waste.

Landfill gas is produced by organic waste decomposing under anaerobic conditions in a landfill. The waste is covered and compressed mechanically and by the weight of the material that is deposited from above. This material prevents oxygen from accessing the waste and anaerobic microbes thrive. This gas builds up and is slowly released into the atmosphere if the landfill site has not been engineered to capture the gas. Landfill gas is hazardous for three key reasons. Landfill gas becomes explosive when it escapes from the landfill and mixes with oxygen within lower and higher explosive limits. The methane in biogas forms explosive mixtures in air. The lower explosive limit is 5% methane and the upper explosive limit is 15% methane.^[1] The methane contained within biogas is 20 times more potent as a greenhouse gas than carbon dioxide. Therefore uncontained landfill gas which escapes into the atmosphere significantly contributes to the effects of global warming. In addition to this volatile organic compounds (VOCs) contained within landfill gas contribute to the formation of photochemical smog.

Composition

The composition of biogas varies depending upon the origin of the anaerobic digestion process. Landfill gas typically has methane concentrations around 50%. Advanced waste treatment technologies can produce biogas with 55-75%CH₄ ^[3].

Main article: Siloxanes

In some cases biogas contains siloxanes. These siloxanes are formed from the anaerobic decomposition of materials commonly found in soaps and detergents. During combustion of biogas containing siloxanes, silicon is released and can combine with free oxygen or various other elements in the combustion gas. Deposits are formed containing mostly silica (SiO₂) or silicates (Si_xO_y) and can also contain calcium, sulphur, zinc, phosphorus. These white mineral deposits build to a surface thickness of several millimetres and must be removed by chemical or mechanical means.

Applications

Biogas can be utilised for electricity production, space heating, water heating and process heating. If compressed, it can replace compressed natural gas for use in vehicles, where it can fuel an internal combustion engine or fuel cells.

In India biogas produced from the anaerobic digestion of manure in small-scale digestion facilites is called Gober gas. In India biogas is generated at an estimated 2 million+ household facilites. The digester is an airtight circular pit made of concrete with a pipe connection. The manure is directed to the pit, usually directly from the cattle shed. The pit is then filled with a required quantity of wastewater. The gas pipe is connected to the kitchen fire place through control valves. The combustion of the biogas produced in this manner flammable has very little odour or smoke. Owing to its simplicity in implementation and use of cheap raw materials in the villages it is one of the most environmentally sound energy source for the rural needs.

Methane within biogas can be concentrated to the same standards as natural gas, when it is called biomethane. If the local gas network permits it the producer of the biogas may be able to utilise the local gas distribution networks. Gas must be very clean to reach pipeline quality, and must be of the correct composition for the local distribution network to accept. Carbon dioxide, Water, hydrogen sulfide and particulates must be removed if present. If concentrated and compressed it can also be used in vehicle transportation. Compressed biogas is becoming widely used in Sweden, Switzerland and Germany. A biogas-powered train has been in service in Sweden since 2005.^[4][5]

Bates' and his biogas car were the subject of a short documentary film called 'Sweet as a Nut' in 1974, at which point he had run his car for 17 years on gas he had produced by processing pig manure. Bates, an inventor lived in Devon, UK and in the film talks through the simple process and benefits of running a car on biogas. The conversion was simply made with an adapter attached to any combustion engine.

Legislation

The European Union presently has some of the strictest legislation regarding waste management and landfill sites called the Landfill Directive. The United States legislates against landfill gas as it contains these VOCs. The United States Clean Air Act and Title 40 of the Code of Federal Regulations (CFR) requires landfill owners to estimate the quantity of non-methane organic compounds (NMOCs) emitted. If the estimated NMOC emissions exceeds 50 tonnes per year the landfill owner is required to collect the landfill gas and treat it to remove the entrained NMOCs. Treatment of the landfill gas is usually by combustion. Because of the remoteness of landfill sites it is sometimes not economically feasible to produce electricity from the gas.

See also

• Biodegradability
• Tables of European biogas utilisation
• Biofuel
• Landfill gas monitoring
• Natural gas vehicle
• Renewable energy
• Renewable natural gas
• Waste management

References

1. ^ Safety Page, Beginners Guide to Biogas, www.adelaide.edu.au/biogas, retrieved 22.10.07
2. ^ Basic Information on Biogas, www.kolumbus.fi, retrieved 2.11.07
3. ^ Juniper Biogas Yield Comparison
4. ^ Biogas train in Sweden
5. ^ Friendly fuel trains (Oct. 30, 2005) New Straits Times, p. F17.