Naturally occurring niobium (Nb) is composed of one stable isotope (Nb-93). The most stable radioisotopes are Nb-92 with a half-life of 34.7 million years, Nb-94 (half life: 20300 years), and Nb-91 with a half life of 680 years. There is also a meta state at 31 keV whose half-life is 16.13 years. Twenty three other radioisotopes have been characterized. Most of these have half lives that are less than two hours except Nb-95 (35 days), Nb-96 (23.4 hours) and Nb-90 (14.6 hours). The primary decay mode before the stable Nb-93 is electron capture and the primary mode after is beta emission with some neutron emission occurring in the first mode of the two mode decay of Nb-104, 109 and 110.
Additional recommended knowledge
Only Nb-95 (35 days) and Nb-97 (72 minutes) and heavier isotopes (halflives in seconds) are fission products in significant quantity, as the other isotopes are shadowed by stable or very long-lived (Zr-93) isotopes of the preceding element zirconium from production via beta decay of neutron-rich fission fragments. Nb-95 is the decay product of Zr-95 (64 days), so disappearance of Nb-95 in used nuclear fuel is slower than would be expected from its own 35 day halflife alone.. Tiny amounts of the other isotopes may be produced as direct fission products.
Standard atomic mass: 92.90638(2) u
Table
nuclide symbol
| Z(p)
| N(n)
| isotopic mass (u)
| half-life
| nuclear spin
| representative isotopic composition (mole fraction)
| range of natural variation (mole fraction)
|
excitation energy
|
81Nb
| 41
| 40
| 80.94903(161)#
| <44 ns
| 3/2-#
|
|
|
82Nb
| 41
| 41
| 81.94313(32)#
| 51(5) ms
| 0+
|
|
|
83Nb
| 41
| 42
| 82.93671(34)
| 4.1(3) s
| (5/2+)
|
|
|
84Nb
| 41
| 43
| 83.93357(32)#
| 9.8(9) s
| 3+
|
|
|
84mNb
| 338(10) keV
| 103(19) ns
| (5-)
|
|
|
85Nb
| 41
| 44
| 84.92791(24)
| 20.9(7) s
| (9/2+)
|
|
|
85mNb
| 759.0(10) keV
| 12(5) s
| (1/2-)
|
|
|
86Nb
| 41
| 45
| 85.92504(9)
| 88(1) s
| (6+)
|
|
|
86mNb
| 250(160)# keV
| 56(8) s
| high
|
|
|
87Nb
| 41
| 46
| 86.92036(7)
| 3.75(9) min
| (1/2-)
|
|
|
87mNb
| 3.84(14) keV
| 2.6(1) min
| (9/2+)#
|
|
|
88Nb
| 41
| 47
| 87.91833(11)
| 14.55(6) min
| (8+)
|
|
|
88mNb
| 40(140) keV
| 7.8(1) min
| (4-)
|
|
|
89Nb
| 41
| 48
| 88.913418(29)
| 2.03(7) h
| (9/2+)
|
|
|
89mNb
| 0(30)# keV
| 1.10(3) h
| (1/2)-
|
|
|
90Nb
| 41
| 49
| 89.911265(5)
| 14.60(5) h
| 8+
|
|
|
90m1Nb
| 122.370(22) keV
| 63(2) µs
| 6+
|
|
|
90m2Nb
| 124.67(25) keV
| 18.81(6) s
| 4-
|
|
|
90m3Nb
| 171.10(10) keV
| <1 µs
| 7+
|
|
|
90m4Nb
| 382.01(25) keV
| 6.19(8) ms
| 1+
|
|
|
90m5Nb
| 1880.21(20) keV
| 472(13) ns
| (11-)
|
|
|
91Nb
| 41
| 50
| 90.906996(4)
| 680(130) a
| 9/2+
|
|
|
91m1Nb
| 104.60(5) keV
| 60.86(22) d
| 1/2-
|
|
|
91m2Nb
| 2034.35(19) keV
| 3.76(12) µs
| (17/2-)
|
|
|
92Nb
| 41
| 51
| 91.907194(3)
| 3.47(24)E+7 a
| (7)+
|
|
|
92m1Nb
| 135.5(4) keV
| 10.15(2) d
| (2)+
|
|
|
92m2Nb
| 225.7(4) keV
| 5.9(2) µs
| (2)-
|
|
|
92m3Nb
| 2203.3(4) keV
| 167(4) ns
| (11-)
|
|
|
93Nb
| 41
| 52
| 92.9063781(26)
| STABLE
| 9/2+
| 1.0000
|
|
93mNb
| 30.77(2) keV
| 16.13(14) a
| 1/2-
|
|
|
94Nb
| 41
| 53
| 93.9072839(26)
| 2.03(16)E+4 a
| (6)+
|
|
|
94mNb
| 40.902(12) keV
| 6.263(4) min
| 3+
|
|
|
95Nb
| 41
| 54
| 94.9068358(21)
| 34.991(6) d
| 9/2+
|
|
|
95mNb
| 235.690(20) keV
| 3.61(3) d
| 1/2-
|
|
|
96Nb
| 41
| 55
| 95.908101(4)
| 23.35(5) h
| 6+
|
|
|
97Nb
| 41
| 56
| 96.9080986(27)
| 72.1(7) min
| 9/2+
|
|
|
97mNb
| 743.35(3) keV
| 52.7(18) s
| 1/2-
|
|
|
98Nb
| 41
| 57
| 97.910328(6)
| 2.86(6) s
| 1+
|
|
|
98mNb
| 84(4) keV
| 51.3(4) min
| (5+)
|
|
|
99Nb
| 41
| 58
| 98.911618(14)
| 15.0(2) s
| 9/2+
|
|
|
99mNb
| 365.29(14) keV
| 2.6(2) min
| 1/2-
|
|
|
100Nb
| 41
| 59
| 99.914182(28)
| 1.5(2) s
| 1+
|
|
|
100mNb
| 470(40) keV
| 2.99(11) s
| (4+,5+)
|
|
|
101Nb
| 41
| 60
| 100.915252(20)
| 7.1(3) s
| (5/2#)+
|
|
|
102Nb
| 41
| 61
| 101.91804(4)
| 1.3(2) s
| 1+
|
|
|
102mNb
| 130(50) keV
| 4.3(4) s
| high
|
|
|
103Nb
| 41
| 62
| 102.91914(7)
| 1.5(2) s
| (5/2+)
|
|
|
104Nb
| 41
| 63
| 103.92246(11)
| 4.9(3) s
| (1+)
|
|
|
104mNb
| 220(120) keV
| 940(40) ms
| high
|
|
|
105Nb
| 41
| 64
| 104.92394(11)
| 2.95(6) s
| (5/2+)#
|
|
|
106Nb
| 41
| 65
| 105.92797(21)#
| 920(40) ms
| 2+#
|
|
|
107Nb
| 41
| 66
| 106.93031(43)#
| 300(9) ms
| 5/2+#
|
|
|
108Nb
| 41
| 67
| 107.93484(32)#
| 0.193(17) s
| (2+)
|
|
|
109Nb
| 41
| 68
| 108.93763(54)#
| 190(30) ms
| 5/2+#
|
|
|
110Nb
| 41
| 69
| 109.94244(54)#
| 170(20) ms
| 2+#
|
|
|
111Nb
| 41
| 70
| 110.94565(54)#
| 80# ms [>300 ns]
| 5/2+#
|
|
|
112Nb
| 41
| 71
| 111.95083(75)#
| 60# ms [>300 ns]
| 2+#
|
|
|
113Nb
| 41
| 72
| 112.95470(86)#
| 30# ms [>300 ns]
| 5/2+#
|
|
|
Notes
- Values marked # are not purely derived from experimental data, but at least partly from systematic trends. Spins with weak assignment arguments are enclosed in parentheses.
- Uncertainties are given in concise form in parentheses after the corresponding last digits. Uncertainty values denote one standard deviation, except isotopic composition and standard atomic mass from IUPAC which use expanded uncertainties.
References
- Isotope masses from Ame2003 Atomic Mass Evaluation by G. Audi, A.H. Wapstra, C. Thibault, J. Blachot and O. Bersillon in Nuclear Physics A729 (2003).
- Isotopic compositions and standard atomic masses from Atomic weights of the elements. Review 2000 (IUPAC Technical Report). Pure Appl. Chem. Vol. 75, No. 6, pp. 683-800, (2003) and Atomic Weights Revised (2005).
- Half-life, spin, and isomer data selected from these sources. Editing notes on this article's talk page.
- Audi, Bersillon, Blachot, Wapstra. The Nubase2003 evaluation of nuclear and decay properties, Nuc. Phys. A 729, pp. 3-128 (2003).
- National Nuclear Data Center, Brookhaven National Laboratory. Information extracted from the NuDat 2.1 database (retrieved Sept. 2005).
- David R. Lide (ed.), Norman E. Holden in CRC Handbook of Chemistry and Physics, 85th Edition, online version. CRC Press. Boca Raton, Florida (2005). Section 11, Table of the Isotopes.
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