Formal charge

The formal charge can be calculated by the following equation: FC = number of valence electrons of the atom - number of lone pair electrons on this atom - half the total number of electrons participating in covalent bonds with this atom.

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When determining the correct Lewis structure (or predominant resonance structure) for a molecule, the structure is chosen such that the formal charge on each of the atoms is minimized.

Examples:

• carbon in methane: FC = 4 - 0 - 8/2 = 0
• Nitrogen in the nitro group NO₂^-: FC = 5 - 2 - 6/2 = 0
• double bonded oxygen in NO₂^-: FC = 6 - 4 - 4/2 = 0
• single bonded oxygen in NO₂^- FC = 6 - 6 - 2/2 = -1

An alternative method for assigning charge to an atom taking into account electronegativity is by oxidation number. Other related concepts are valence which counts number of electrons that an atom uses in bonding and coordination number, the number of atoms bonded to the atom of interest.

Examples

Ammonium NH₄⁺ is a cationic species. By using the vertical groups of the atoms on the periodic table it is possible to determine that each hydrogen contributes 1 electron, the nitrogen contributes 5 electrons, and the charge of +1 means that 1 electron is absent. The final total is 8 total electrons (1 × 4 + 5 − 1). Drawing the Lewis structure gives an sp³ (4 bonds) hybridized nitrogen atom surrounded by hydrogen. There are no lone pairs of electrons left. Thus, using the definition of formal charge, hydrogen has a formal charge of zero (1-(0 + ½ × 2)) and nitrogen has a formal charge of +1 (5−(0 + ½ × 8)). After adding up all the formal charges throughout the molecule the result is a total formal charge of +1, consistent with the charge of the molecule given in the first place.

Note: The total formal charge in a molecule should be as close to zero as possible, with as few charges on the molecule as possible

• Example: CO₂ is a neutral molecule with 16 total valence electrons. There are three different ways to draw the Lewis structure
  • Carbon single bonded to both oxygen atoms (carbon = +2, oxygens = -1 each, total formal charge = 0)
  • Carbon single bonded to one oxygen and double bonded to another (carbon = +1, oxygen_double = 0, oxygen_single = −1, total formal charge = 0)
  • Carbon double bonded to both oxygen atoms (carbon = 0, oxygens = 0, total formal charge =0)

Even though all three structures gave us a total charge of zero, the final structure is the superior one because there are no charges in the molecule at all

Alternative method

Although the formula given above is correct, it is often unwieldy and inefficient to use. A much quicker and still accurate method is to do the following:

• Draw a circle around the atom for which the formal charge is requested (as with carbon dioxide, below)

• Count up the number of electron in the atom's "circle." Since the circle cuts the covalent bond "in half," each covalent bond counts as one electron instead of two.
• Subtract the number of electrons in the circle from the group number of the element (the roman numeral from the older system of group numbering, NOT the IUPAC 1-18 system) to determine the formal charge. (aka: old group number minus electrons in circle)

• The formal charges computed for the remaining atoms in this Lewis structure of carbon dioxide are shown below.

Again, this method is just as accurate as the one cited above, but is much easier to use. It is important to keep in mind that formal charges are just that-formal, in the sense that this system is a formalism. Atoms in molecules do not have "signs around their necks" indicating their charge. The formal charge system is just a method to keep track of all of the valence electrons that each atom brings with it when the molecule is formed.