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Ferrier rearrangementThe Ferrier rearrangement is an organic reaction that involves a nucleophilic substitution reaction combined with an allylic shift in a 2,3-Unsaturated glycoside (see glycals). Additional recommended knowledgeIn this example of a Ferrier rearrangement tri-O-acetyl-D-glucal (OAc stands for acetate groups) reacts with methanol as the aglycon and indium chloride as a Lewis acid in dichloromethane to a mixture 7:1 of the α (1) and β (2) anomer. Further examples are shown below. References
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This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Ferrier_rearrangement". A list of authors is available in Wikipedia. |