Doppler cooling limit

Doppler temperature is the minimum temperature achievable with Doppler cooling, one of the methods of laser cooling.

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When a photon is absorbed by an atom moving in the opposite direction, its velocity is decreased according to the laws of momentum conservation. Accordingly, when a photon is emitted by this excited atom, there is an extra momentum added to the atom. But since emission is non-directional, this effect "averages" out, and on a time average, there is just a little increase in the atom's momentum due to emission. At the temperature when this effect exactly balances out the cooling effect of the laser, no further cooling is possible. It turns out that it is equal to where γ is the natural linewidth of the atomic transition, k_B is the Boltzmann's constant and is the reduced Planck constant.

The term Doppler arises from the fact that the Doppler effect, which provides a velocity dependence of the absorption rate and thus the light force, is an essential ingredient of the Doppler cooling mechanism.

Temperatures well below the Doppler limit have been achieved with various laser cooling methods, including Sisyphus cooling, which allows to approach the lower so-called recoil limit.