Celsian

Celsian is an uncommon feldspar mineral, barium aluminosilicate, BaAl₂Si₂O₈. The mineral occurs in contact metamorphic rocks with significant barium content. Its crystal system is monoclinic, and it is white, yellow, or transparent in appearance. In pure form, it is transparent. Synthetic barium aluminosilicate is used as a ceramic in dental fillings and other applications.

The mineral is named after Anders Celsius.

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Composition

Celsian is a barium feldspar with a chemical composition BaAl₂Si₂O₈. It forms part of the feldspar group and belongs to the celsian-hyalophane series and the celsian-orthoclase series. It has some resemblance to anorthite, and it has four distinct polymorphs. The essential elements are Si,Al,O and Ba. Some common impurities in the mineral are Fe, Ti, Mg,K and Ca. Celsian is stable from room temperature up to 1590 °C ( Lin and Foster,1968) .The most common trace elements are potassium and calcium, in an analisis of the approximate chemical composition of celsian the following wt% were found: • SiO₂—35.1 • Al₂O₃---26.8 • BaO----35.8 • K₂O-----2.3 Total:100.0 (Newham and Megaw,1960).

Geologic occurrence

Celsian is of limited occurrence. Most of the barium feldspars are associated with exhalative hydrothermal processes and low-and medium-grade metamorphism (Moro and Cembranos and Fernandez, 2001). It is also associated with sedimentary and meta sedimentary rocks, manganese, ferromanganese and barite deposits. Barium is rarely found in its pure form since it quickly oxidizes with air, it is more commonly found and extracted from barite, in other cases the barium may be present due to metamorphic events.

Celsian can be found in places like Wales, Zamora (Spain), Alaska, California, Sweden and Japan, also with hendricksite on the Franklin mines in New Jersey (N.J), others locations of Celsian are showned in figure 1.

Figure 1: location of celsian. http://www.mindat.org/min-928.html

Structure

The symmetry in celsian is somewhat different to the symmetry normally found in feldspars. It is monoclinic with a body centered lattice similar to those of anorthite. Not sufficient evidence has been found to suggest that celsian lacks a center of symmetry, so its space group is I 2/c (Newnham and Megaw, 1960). The space group differs from others of its group like orthoclase, albite and body center anorthite are C2/m, C1bar and I1bar.

X-ray analysis shows that the values for the lattice parameters a, b, c axes and angles are approximately a=863 pm, b=131.0 pm, c=1400 pm and β=116°, θ=90°(Gay, 1956).

There are 8 formula units per cell, and the general position is eightfold, so all atoms can lie in general positions (Newnham and Megaw,1960). This structure is very similar to that of orthoclase and sanidine but differs in a couple of ways: 1. The distribution of Si and Al. 2. The coordinates of all the atoms. The distribution of silicon and aluminum along the tetrahedral sites mixed with the nature of the barium atom makes an impact on the surrounding silicate framework (Newham and Megaw,1960). The Si-Al bonds are partially ordered, and in some cases the aluminum substitute’s silicon.

The order in celsian is very simple, each aluminum tetrahedron is surrounded by four silicon tetrahedral, and vice versa (Newham and Megaw,1960). Also there is another type of transformation besides aluminum-silicon, where silicon-poor goes into a silicon-rich network that involves having to simultaneously be a replacement of Al, and Si at other sites.

The barium ion has an irregular configuration close to the one in potassium in the feldspars. Each barium has an oxygen close, and thanks to this configuration it has a strong effect on the silicon-oxygen-silicon bond angles.

Polymorphism of Celsian

There are four distinctive polymorphs of Celsian, two of them are the natural minerals and the other two are synthetic products. The first are paracelsian and celsian, the second ones are hexacelsian and the other one is related to the mineral cymrite (Lin and foster, 1967). The order of increasing stability is paracelsian→hexacelsian→celsian in a temperature range between 5000C to the 10000C.

As temperature rises from the 16000C to 17600C it goes from celsian[1] to a reversible form of hexacelsian. Paracelsian is less stable than the other two and Celsian is the most stable.

TwiningBarium feldspars occur in optically uniform crystals where the twining is poorly developed, except on coarse crystals. Eighteen crystals forms have been identify eleven of them coincide with those known for the orthoclase. On this structures it was found manebach twins on (001), baveno twins (021). Some samples of celsian were found to have a rare lamellar twinning (Spencer, 1941). Figure 5 : Celsian crystals from Benalt mine, Carnavoshire. (spencer,1941)

Physical properties

Celsian shows a c(001) perfect cleavage and a b(010) good cleavage, which marks the difference with its polymorph paracelsian which has a [110] indistinct cleavage.There are different crystals habits like adularia, larger, snout crystals (spencer,1941), and long, slender to acicular. It is usually colorless and transparent with a pearly to non-florescent luster.

The density is about 3.31 to 3.33 g/cm³. This might be the case due to some impurities in the structure of the mineral. It has a hardness of 6 on the Moh’s scale, this hardness is due to the short length of the bond in the structure, since is relative short tends to be harder. Some optical properties

Some other optical properties are the 2V angle which is approximately 880 with a maximum birefringence of 0.014, biaxial with a negative sign (Newnham and Megaw, 1960). It has a moderate relief.

Uses

Celsian has very attractive features such as chemical stability and high mechanical resistance, which can be favourably exploited in order to obtain enhanced-performance composites with respect to bulk glass. (Cannillo , Carlier , Manfredini , Montorsi ,and Siligardi 2006). Many studies shows that by increasing the amount of celsian phases in the glases results in increased bulk of crytaslization.(Khater and Idris, 2004)

The uses of celsian are mostly related to glass and ceramics. This uses are usually achieved by the preparation of pure monoclinic celsian.

References

• "Celsian Mineral Data". Retrieved August 7, 2005.

Cannillo V, Carlier E, Manfredini T, Montorsi M, Siligardi C. Design and optimisation of glass-celsian composites COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING.2006, vol 37, pp 23-30

Gay P. A note on celsian. Acta Cryst., 1956, vol 9, pp 474.

Khater G, Idris M. The use of a Saudi kaolinitic clay for the production glass-ceramic materials. Indus. Ceramics. 2004, vol 24, pp 43-50

Lin H.C and Foster W.R.The polymorphism of Celsian. The Canadian min., 1967, vol 9 , pp 295.

Lin H.C and Foster W.R. Studies in the system Ba0-Al2O3Si02. The polymorphism of Celsian.Amer. Min.,1968, vol 53, pp 134-144

Moro M.C, Cembranos M.L and Fernandez A. Celsian, (Ba,K)-feldspas and cymrite from sedex barite deposits of Zamora, Spain. The Canad. Min. 2001, vol 39, pp1039-1051.

Newham R.W and Megaw H.D. The crystal structure of celsian (barium feldspar). Acta Cryst., 1960, vol 13, pp 303-312

Spencer L.j. Barium-feldspar (celsian and paracelsian) from wales.The min. mag., 1942,vol 26, pp.231-243.