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CBS reductionThe CBS reduction, in full the Corey-Bakshi-Shibata reduction, is an organic reaction which transforms ketones enantioselectively into alcohols.[1][2][3] This is done by using the so-called CBS catalyst, a bicyclic boron-containing proline derivative, along with diborane as the hydrogen donor.[4][5][6] Additional recommended knowledgeThe oxazaborolidine reagent which mediates the enantioselective reduction was previously developed by the laboratory of Itsuno,[7] and thus this transformation may more properly be called the Itsuno-Corey oxazaborolidine reduction. References
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This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "CBS_reduction". A list of authors is available in Wikipedia. |