Basalt

Basalt (pronounced /ˈbæsɒlt, bəˈsɔːlt/) is a common gray to black extrusive volcanic rock. It is usually fine-grained due to rapid cooling of lava on the Earth's surface. It may be porphyritic containing larger crystals in a fine matrix, or vesicular, or frothy scoria. Unweathered basalt is black or gray.

Basalt magmas have formed by decompression melting of the Earth's mantle and by partial melting of rock in the interiors of Mars and the Earth's moon. Source rocks for the partial melts probably include both peridotite and pyroxenite (e.g., Sobolev et al., 2007). The crustal portions of oceanic tectonic plates are composed predominantly of basalt, produced from upwelling mantle below ocean ridges.

The term basalt is at times applied to shallow intrusive rocks with a composition typical of basalt, but rocks of this composition with a phaneritic (coarse) groundmass are generally referred to as dolerite (also called diabase) or gabbro.  

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Essential Laboratory Skills Guide

Types of basalt

• Tholeiitic basalt is relatively poor in silica and poor in sodium. Included in this category are most basalts of the ocean floor, most large oceanic islands, and continental flood basalts such as the Columbia River Plateau.
  • MORB (Mid Ocean Ridge Basalt), is characteristically low in incompatible elements. MORB is commonly erupted only at ocean ridges. MORB itself has been subdivided into varieties such as NMORB and EMORB (slightly more enriched in incompatible elements).^{[1] [2]}

• High alumina basalt may be silica-undersaturated or -oversaturated (see normative mineralogy). It has greater than 17% alumina (Al₂O₃) and is intermediate in composition between tholeiite and alkali basalt; the relatively alumina-rich composition is based on rocks without phenocrysts of plagioclase.

• Alkali basalt is relatively poor in silica and rich in sodium. It is silica-undersaturated and may contain feldspathoids, alkali feldspar and phlogopite.

• Boninite is a high-magnesium form of basalt or andesite that is erupted generally in back-arc basins, distinguished by its low titanium content and trace element composition.

Petrology

The mineralogy of basalt is characterized by a preponderance of calcic plagioclase feldspar and pyroxene. Olivine can also be a significant constituent. Accessory minerals present in relatively minor amounts include iron oxides and iron-titanium oxides, such as magnetite, ulvospinel, and ilmenite. Because of the presence of such oxide minerals, basalt can acquire strong magnetic signatures as it cools, and paleomagnetic studies have made extensive use of basalt.

In tholeiitic basalt, pyroxene (augite and orthopyroxene or pigeonite) and calcium-rich plagioclase are common phenocryst minerals. Olivine may also be a phenocryst, and when present, may have rims of pigeonite. The groundmass contains interstitial quartz or tridymite or cristobalite. Olivine tholeiite has augite and orthopyroxene or pigeonite with abundant olivine, but olivine may have rims of pyroxene and is unlikely to be present in the groundmass.

In high-alumina basalts, phenocrysts of feldspar commonly are bytownite in composition. Other common phenocryst minerals are olivine and augite; orthopyroxene is less common. Silica minerals and/or alkali feldspar may be present in the groundmass.

Alkali basalts typically have mineral assemblages that lack orthopyroxene but contain olivine. Feldspar phenocrysts typically are labradorite to andesine in composition. Augite is rich in titanium compared to augite in tholeiitic basalt. Minerals such as alkali feldspar, leucite, nepheline, sodalite, phlogopite mica, and apatite may be present in the groundmass.

Basalt has high liquidus and solidus temperatures -- values at the Earth's surface are near or above 1200 °C (liquidus) and near or below 1000 °C (solidus); these values are higher than those of other common igneous rocks.

The majority of tholeiites are formed at approximately 50-100 km depth within the mantle. Many alkali basalts may be formed at greater depths, perhaps as deep as 150-200 km. The origin of high-alumina basalt continues to be controversial, with interpretations that it is a primary melt and that instead it is derived from other basalt types (e.g., Ozerov, 2000).

Geochemistry

Basalt compositions are rich in MgO and CaO and low in SiO₂ and Na₂O plus K₂O relative to most common igneous rocks, consistent with the TAS classification.

Basalt generally has a composition of 45-55 wt% SiO₂, 2-6 wt% total alkalis, 0.5-2.0 wt% TiO₂, 5-14 wt% FeO and 14 wt% or more Al₂O₃. Contents of CaO are commonly near 10 wt%, those of MgO commonly in the range 5 to 12 wt%.

High alumina basalts have aluminium contents of 17-19 wt% Al₂O₃; boninites have magnesium contents of up to 15% MgO. Rare feldspathoid-rich mafic rocks, akin to alkali basalts, may have Na₂O plus K₂O contents of 12% or more.

MORB basalts and their intrusive equivalents, gabbros, are the characteristic igneous rocks formed at mid-ocean ridges. They are tholeiites particularly low in total alkalis and in incompatible trace elements, and they have relatively flat REE patterns normalised to mantle or chondrite values. In contrast, alkali basalts have normalized patterns highly enriched in the light REE, and with greater abundances of the REE and of other incompatible elements. Because MORB basalt is considered a key to understanding plate tectonics, its compositions have been much studied. Although MORB compositions are distinctive relative to average compositions of basalts erupted in other environments, they are not uniform. For instance, compositions change with position along the Mid-Atlantic ridge, and the compositions also define different ranges in different ocean basins (Hofmann, 2003).

Isotope ratios of elements such as strontium, neodymium, lead, hafnium, and osmium in basalts have been much-studied, so as to learn about evolution of the Earth's mantle. Isotopic ratios of noble gases, such as ³He/⁴He, are also of great value: for instance, ratios for basalts range from 6 to 10 for mid-ocean ridge tholeiite (normalized to atmospheric values), but to 15-24+ for ocean island basalts thought to be derived from mantle plumes.

Morphology and textures

The shape, structure and texture of a basalt is diagnostic of how and where it erupted - whether into the sea, in an explosive cinder eruption or as creeping pahoehoe lava flows, the classical image of Hawaiian basalt eruptions.  

Subaerial eruptions

Basalt which erupts under open air (that is, subaerially) forms three distinct types of lava or volcanic deposits: scoria, ash or cinder; breccia and lava flows.

Basalt in the tops of subaerial lava flows and cinder cones will often be highly vesiculated, imparting a lightweight "frothy" texture to the rock. Basaltic cinders are often red, coloured by oxidised iron from weathered iron-rich minerals such as pyroxene.

‘A‘a types of blocky, cinder and breccia flows of thick, viscous basaltic lava are common in Hawaii. Pahoehoe is a highly fluid, hot form of basalt which tends to form thin aprons of molten lava which fill up hollows and sometimes forms lava lakes. Lava tubes are common features of pahoehoe eruptions.

Basaltic tuff or pyroclastic rocks are rare but not unknown. Usually basalt is too hot and fluid to build up sufficient pressure to form explosive lava eruptions but occasionally this will happen by trapping of the lava within the volcanic throat and build up of volcanic gases. Hawaii's Mauna Loa volcano erupted in this way in the 19th century, as did Mount Tarawera, New Zealand in its violent 1886 eruption. Another example is the 0.2 Ma Diamond Head Tuff, Hawaii.   Maar volcanoes are typical of small basalt tuffs, formed by explosive eruption of basalt through the crust, forming an apron of mixed basalt and wall rock breccia and a fan of basalt tuff further out from the volcano.

Amygdaloidal structure is common in relict vesicles and beautifully crystallized species of zeolites, quartz or calcite are frequently found.

Columnar basalt

During the cooling of a thick lava flow, contractional joints or fractures form. If a flow cools relatively rapidly, significant contraction forces build up. While a flow can shrink in the vertical dimension without fracturing, it cannot easily accommodate shrinking in the horizontal direction unless cracks form. The extensive fracture network that develops results in the formation of columns. The topology of the lateral shapes of these columns can broadly be classed as a random cellular network. These structures are often erroneously described as being predominantly hexagonal. In reality, the mean number of sides of all the columns in such a structure is indeed six (by geometrical definition), but polygons with three to twelve or more sides can be observed^[3]. Note that the size of the columns depends loosely on the rate of cooling; very rapid cooling may result in very small (<1 cm diameter) columns, and vice versa.

Perhaps the most famous basalt flow in the world is the Giant's Causeway on the northern coast of Ireland, in which the vertical joints form hexagonal columns and give the impression of having been artificially constructed.

An ancient 13th century religious complex, called Nan Madol, was built on the Pacific island of Pohnpei, using columnar basalt quarried from various locations on the island. The massive ruins remain to this day.

• Famous columnar basalts:
  • Giant's Causeway, Northern Ireland
  • Devil's Postpile, California
  • Narooma Basalt, Narooma, New South Wales, Australia
  • Samson's ribs, Scotland
  • Staffa, Scotland
  • Devil's Tower, Wyoming
  • Pwisehn Malek, Pohnpei, Federated States of Micronesia ^[4]
  • Basalt Island area, Hong Kong; including High Island Reservoir area, Hong Kong SAR, China

Submarine eruptions

Pillow basalts

When basalt erupts underwater or flows into the sea, the cold water quenches the surface and the lava forms a distinctive pillow shape, through which the hot lava breaks to form another pillow. This pillow texture is very common in underwater basaltic flows and is diagnostic of an underwater eruption environment when found in ancient rocks. Pillows typically consist of a fine-grained core with a glassy crust and have radial jointing. The size of individual pillows varies from 10 cm up to several metres.

When pahoehoe lava enters the sea it usually forms pillow basalts. However when a'a enters the ocean it forms a littoral cone, a small cone-shaped accumulation of tuffaceous debris formed when the blocky a'a lava enters the water and explodes from built-up steam.

The island of Surtsey in the Atlantic Ocean is a basalt volcano which breached the ocean surface in 1963. The initial phase of Surtsey's eruption was highly explosive, as the magma was quite wet, causing the rock to be blown apart by the boiling steam to form a tuff and cinder cone. This has subsequently moved to a typical pahoehoe type behaviour.

Volcanic glass may be present, particularly as rinds on rapidly chilled surfaces of lava flows, and is commonly (but not exclusively) associated with underwater eruptions.

Life on basaltic rocks

The common corrosion features of underwater volcanic basalt suggest that microbial activity may play a significant role in the chemical exchange between basaltic rocks and seawater. The significant amounts of reduced iron, Fe(II), and manganese, Mn(II), present in basaltic rocks provide potential energy sources for bacteria. Recent research has shown that some Fe(II)-oxidizing bacteria cultured from iron-sulfide surfaces are also able to grow with basaltic rock as a source of Fe(II).^[5] In recent work at Loihi Seamount, Fe- and Mn- oxidizing bacteria have been cultured from weathered basalts.^[6] The impact of bacteria on altering the chemical composition of basaltic glass (and thus, the oceanic crust) and seawater suggest that these interactions may lead to an application of hydrothermal vents to the origin of life.

Distribution

  The lava flows of the Deccan Traps in India, the Paraná Traps in Brazil, the Siberian Traps in Russia, the Columbia River Plateau of Washington and Oregon, as well as parts of the California inner coastal ranges in the United States, as well as the Triassic lavas of eastern North America are basalts. Other famous accumulations of basalts include Iceland, the Karoo flood basalt province in South Africa and the islands of the Hawaii volcanic chain, forming above a mantle plume. Basalt is the rock most typical of large igneous provinces.

Ancient Precambrian basalts are usually only found in fold and thrust belts, and are often heavily metamorphosed. These are known as greenstone belts, because low-grade metamorphism of basalt produces chlorite, actinolite, epidote and other green minerals.

Lunar and Martian basalt

The dark areas visible on Earth's moon, the lunar maria, are plains of flood basaltic lava flows. These rocks were sampled by the manned American Apollo program, the robotic Russian Luna program, and are represented among the lunar meteorites.

Lunar basalts differ from their terrestrial counterparts principally in their high iron contents, which typically range from about 17 to 22 wt% FeO. They also possess a stunning range of titanium concentrations (present in the mineral ilmenite), ranging from less than 1 wt% TiO₂, to about 13 wt.%. Traditionally, lunar basalts have been classified according to their titanium content, with classes being named high-Ti, low-Ti, and very-low-Ti. Nevertheless, global geochemical maps of titanium obtained from the Clementine mission demonstrate that the lunar maria possess a continuum of titanium concentrations, and that the highest concentrations are the least abundant.

Lunar basalts show exotic textures and mineralogy, particularly shock metamorphism, lack of the oxidation typical of terrestrial basalts, and a complete lack of hydration. While most of the Moon's basalts erupted between about 3 and 3.5 billion years ago, the oldest samples are 4.2 billion years old, and the youngest flows, based on the age dating method of "crater counting," are estimated to have erupted only 1.2 billion years ago.

Basalt is also a common rock on the surface of Mars, as determined by data sent back from the surface of Mars and by Martian meteorites.

Metamorphism

Basalts are important rocks within metamorphic belts, as they can provide vital information on the conditions of metamorphism within the belt. Various metamorphic facies are named after the mineral assemblages and rock types formed by subjecting basalts to the temperatures and pressures of the metamorphic event. These are;

• Greenschist facies
• Blueschist facies
• Zeolite facies
• Granulite facies
• Eclogite facies

Metamorphosed basalts are important hosts for a variety of hydrothermal ore deposits, including gold deposits, copper deposits, volcanogenic massive sulfide ore deposits and others.

See also

• Basalt fiber
• Mafic rocks
• Volcanoes
• Igneous rocks
• Flood basalt

References

1. ^ See the PETDB database.Hyndman, Donald W. (1985). Petrology of igneous and metamorphic rocks, 2nd ed., McGraw-Hill. ISBN 0-07-031658-9. 
2. ^ Blatt, Harvey and Robert Tracy (1996). Petrology, 2nd ed., Freeman. ISBN 0-7167-2438-3. 
3. ^ D. Weaire and N. Rivier. Contemporary Physics 25 1 (1984), pp. 55–99
4. ^ http://www.pohnpeiheaven.com/pwisehn_malek.htm Alex Zuccarelli, 2003, Pohnpei-Between Time & Tide . Pwisehn Malek
5. ^ Katrina J. Edwards, Wolfgang Bach and Daniel R. Rogers, Geomicrobiology of the Ocean Crust: A Role for Chemoautotrophic Fe-Bacteria, Biol. Bull. 204: 180-185. (April 2003) http://www.biolbull.org/cgi/content/full/204/2/180
6. ^ Templeton, A.S., Staudigel, H., Tebo, B.M. (2005). Diverse Mn(II)-oxidizing bacteria isolated from submarine basalts at Loihi Seamount, Geomicrobiology Journal, v. 22, 129-137. http://www.ebs.ogi.edu/tebob/pdfs/Templeton%20GeomicroJ.pdf

• A. Y. Ozerov, The evolution of high-alumina basalts of the Klyuchevskoy volcano, Kamchatka, Russia, based on microprobe analyses of mineral inclusions. Journal of Volcanology and Geothermal Research, v. 95, p. 65-79 (2000).
• A. W. Hofmann, Sampling mantle heterogeneity through oceanic basalts: isotopes and trace elements. Treatise on Geochemistry Volume 2, pages 61-101 Elsevier Ltd. (2003). ISBN 0-08-044337-0 In March, 2007, the article was available on the web at http://www1.mpch-mainz.mpg.de/~geo/hofmann/Hofmann.mantle_heterogen1.pdf.
• A. V. Sobolev and others, The amount of recycled crust in sources of mantle-derived melts. Science, v. 316, p. 412-417 (2007). http://www.sciencemag.org/cgi/content/abstract/316/5823/412