Svante Arrhenius

Svante August Arrhenius (February 19, 1859 – October 2, 1927) was a Swedish chemist and one of the founders of the science of physical chemistry. The Arrhenius equation and the lunar crater Arrhenius are named after him.

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Early years

Arrhenius was born at Vik (also spelled Wik or Wijk), near Uppsala, Sweden, the son of Svante Gustav and Carolina Thunberg Arrhenius. His father had been a land surveyor for Uppsala University, moving up to a supervisory position. At the age of three, Arrhenius taught himself to read, despite his parents' wishes, and by watching his father's addition of numbers in his account books, became an arithmetical prodigy.

In later life, Arrhenius enjoyed using masses of data to discover mathematical relationships and laws. At age 8, he entered the local cathedral school, starting in the fifth grade, distinguishing himself in physics and mathematics, and graduating as the youngest and most able student in 1876.

At the University of Uppsala, he was unsatisfied with the chief instructor of physics and the only faculty member who could have supervised him in chemistry, Per Teodor Cleve, so he left to study at the Physical Institute of the Swedish Academy of Sciences in Stockholm under the physicist Erik Edlund in 1881. His work focussed on the conductivities of electrolytes. In 1884, based on this work, he submitted a 150-page dissertation on electrolytic conductivity to Uppsala for the doctorate. It did not impress the professors, like Per Teodor Cleve, and he received the lowest possible passing grade. Later this very work would earn him the Nobel Prize in Chemistry.

There were 56 theses put forth in the 1884 dissertation, and most would still be accepted today unchanged or with minor modifications. The most important idea in the dissertation was his explanation of the fact that neither pure salts nor pure water is a conductor, but solutions of salts in water are.

Arrhenius' explanation was that in forming a solution, the salt dissociates into charged particles (which Michael Faraday had given the name ions many years earlier). Faraday's belief had been that ions were produced in the process of electrolysis; Arrhenius proposed that, even in the absence of an electric current, solutions of salts contained ions. He thus proposed that chemical reactions in solution were reactions between ions. For weak electrolytes this is still believed to be the case, but modifications (by Peter J. W. Debye and Erich Hückel) were found necessary to account for the behavior of strong electrolytes.

The dissertation was not very impressive to the professors at Uppsala, but Arrhenius sent it to a number of scientists in Europe who were developing the new science of physical chemistry, such as Rudolf Clausius, Wilhelm Ostwald, and J. H. van 't Hoff. They were far more impressed, and Ostwald even came to Uppsala to persuade Arrhenius to join his research team. Arrhenius declined, however, as he preferred to stay in Sweden for a while (his father was very ill and would die in 1885) and had received an appointment at Uppsala.

Middle period

Arrhenius next received a travel grant from the Swedish Academy of Sciences, which enabled him to study with Ostwald in Riga (now in Latvia), with Friedrich Kohlrausch in Würzburg, Germany, with Ludwig Boltzmann in Graz, Austria, and with van 't Hoff in Amsterdam.

In 1889 Arrhenius explained the fact that most reactions require added heat energy to proceed by formulating the concept of activation energy, an energy barrier that must be overcome before two molecules will react. The Arrhenius equation gives the quantitative basis of the relationship between the activation energy and the rate at which a reaction proceeds.

In 1891 he became a lecturer at Stockholms Högskola (now Stockholm University), being promoted to professor of physics (with much opposition) in 1895, and rector in 1896.

He was married twice, to Sofia Rudbeck (his former pupil), who bore him one son, although the marriage only lasted two years from 1894 to 1896, and to Maria Johansson (who bore him two daughters and a son), from 1905 until his death.

In 1901 Arrhenius was elected to the Swedish Academy of Sciences, against strong opposition. In 1903 he became the first Swede to be awarded the Nobel Prize in chemistry. In 1905, upon the founding of the Nobel Institute for Physical Research at Stockholm, he was appointed rector of the institute, the position where he remained until retirement in 1927. He became a Fellow of the Royal Society in 1910^[1].

Later years

Eventually, Arrhenius' theories became generally accepted and he turned to other scientific topics. In 1902 he began to investigate physiological problems in terms of chemical theory. He determined that reactions in living organisms and in the test tube followed the same laws. In 1904 he delivered at the University of California a course of lectures, the object of which was to illustrate the application of the methods of physical chemistry to the study of the theory of toxins and antitoxins, and which were published in 1907 under the title Immunochemistry. He also turned his attention to geology (the origin of ice ages), astronomy, physical cosmology, and astrophysics, accounting for the birth of the solar system by interstellar collision. He considered radiation pressure as accounting for comets, the solar corona, the aurora borealis, and zodiacal light.

He thought life might have been carried from planet to planet by the transport of spores, the theory now known as panspermia. He thought of the idea of a universal language, proposing a modification of the English language.

In an extension of his ionic theory Arrhenius proposed definitions for acids and bases, in 1884. He believed that acids were substances which produce hydrogen ions in solution and that bases were substances which produce hydroxide ions in solution.

In his last years he wrote both textbooks and popular books, trying to emphasize the need for further work on the topics he discussed.

In September, 1927, he came down with an attack of acute intestinal catarrh, died on October 2, and was buried in Uppsala.

Greenhouse effect as cause for ice ages

Svante Arrhenius developed a theory to explain the ice ages, and first speculated that changes in the levels of carbon dioxide in the atmosphere could substantially alter the surface temperature through the greenhouse effect ("On the Influence of Carbonic Acid in the Air Upon the Temperature of the Ground", Philosophical Magazine 1896(41): 237-76). He was influenced by the work of others, including Joseph Fourier. Arrhenius used the infrared observations of the moon by Frank Washington Very and Samuel Pierpont Langley at the Allegheny Observatory in Pittsburgh to calculate the absorption of CO₂ and water vapour. Arrhenius' painstaking calculations were later shown to be erroneous. Using 'Stefan's law' (better known as the Stefan Boltzmann law), he formulated his greenhouse law. In its original form, Arrhenius' greenhouse law reads as follows:

if the quantity of carbonic acid increases in geometric progression, the augmentation of the temperature will increase nearly in arithmetic progression.

Which is still valid in the simplified expression by Myhre et al. (1998).

ΔF = αln(C/C₀)

Arrhenius' high absorption values for CO₂, however, met criticism by Knut Ångström in 1900, who published the first modern infrared spectrum of CO₂ with two absorption bands. Arrhenius replied strongly in 1901 (Annalen der Physik), dismissing the critique altogether. He touched the subject briefly in a technical book titled Lehrbuch der kosmischen Physik (1903). He later wrote Världarnas utveckling (1906), German translation: Das Werden der Welten (1907), English translation: Worlds in the Making (1908) directed at a general audience, where he suggested that the human emission of CO₂ would be strong enough to prevent the world from entering a new ice age, and that a warmer earth would be needed to feed the rapidly increasing population. He was the first person to predict that emissions of carbon dioxide from the burning of fossil fuels and other combustion processes would cause global warming. Arrhenius clearly believed that a warmer world would be a positive change. From that, the hot-house theory gained more attention. Nevertheless, until about 1960, most scientists dismissed the hot-house / greenhouse effect as implausible for the cause of ice ages as Milutin Milankovitch had presented a mechanism using orbital changes of the earth (Milankovitch cycles), which has proven to be a powerful predictor of most of the past climate changes for millions of years. Nowadays, the accepted explanation is that orbital forcing sets the timing for ice ages with CO₂ acting as an essential amplifying feedback.

Arrhenius estimated that halving of CO₂ would decrease temperatures by 4 - 5 °C and a doubling of CO₂ would cause a temperature rise of 5 - 6 degrees Celsius [1]or 7 - 11 degrees Fahrenheit. Recent (2007) estimates from IPCC say this value (the Climate sensitivity) is likely to be between 2 and 4.5 degrees. What is remarkable is that Arrhenius came so close to the most recent IPCC estimate. Arrhenius expected CO₂ levels to rise at a rate given by emissions in his time. Since then, industrial carbon dioxide levels have risen at a much faster rate: Arrhenius expected CO₂ doubling to take about 3000 years; it is now predicted to take about a century.

See also

• Arrhenius equation
• Acid-base reaction theories

Bibliography

• Svante Arrhenius, 1884, Recherches sur la conductivité galvanique des électrolytes, doctoral dissertation, Stockholm, Royal publishing house, P.A. Norstedt & söner, 89 pages.
• Svante Arrhenius, 1896a, Ueber den Einfluss des Atmosphärischen Kohlensäurengehalts auf die Temperatur der Erdoberfläche, in the Proceedings of the Royal Swedish Academy of Science, Stockholm 1896, Volume 22, I N. 1, pages 1–101.
• Svante Arrhenius, 1896b, On the Influence of Carbonic Acid in the Air upon the Temperature of the Ground, London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science (fifth series), April 1896. vol 41, pages 237–275.
• Svante Arrhenius, 1901a, Ueber die Wärmeabsorption durch Kohlensäure, Annalen der Physik, Vol 4, 1901, pages 690–705.
• Svante Arrhenius, 1901b, Über Die Wärmeabsorption Durch Kohlensäure Und Ihren Einfluss Auf Die Temperatur Der Erdoberfläche. Abstract of the proceedings of the Royal Academy of Science, 58, 25–58.
• Svante Arrhenius, 1903, Lehrbuch der Kosmischen Physik, Vol I and II, S. Hirschel publishing house, Leipzig, 1026 pages.
• Svante Arrhenius, 1908, Das Werden der Welten, Academic Publishing House, Leipzig, 208 pages.

Further reading

• Snelders, H.A.M. (1970). "Arrhenius, Svante August". Dictionary of Scientific Biography 1. New York: Charles Scribner's Sons. 296-301. ISBN 0684101149. 
• Crawford, Elisabeth T. Arrhenius: from ionic theory to the greenhouse effect Canton, MA: Science History Publications. ISBN 0881351660