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Aniline (data page)

This page provides supplementary chemical data on aniline.

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1 Material Safety Data Sheet
2 Structure and properties
3 Thermodynamic properties
4 Vapor pressure of liquid
5 Distillation data
6 Spectral data
- 6.1 UV Absorbance Spectroscopy of Aniline
7 Regulatory data
8 References

Material Safety Data Sheet

The handling of this chemical may incur notable safety precautions. It is highly recommend that you seek the Material Safety Datasheet (MSDS) for this chemical from a reliable source such as SIRI, and follow its directions. MSDS for aniline is available at Mallinckrodt Baker.

Structure and properties

Structure and properties
Index of refraction, n_D	1.5863 at 20°C
Abbe number	?
Dielectric constant,^[1] ε_r	6.89 ε₀ at 20 °C
Bond strength	?
Bond length	?
Bond angle	?
Magnetic susceptibility	?
Surface tension^[2]	44.0 dyn/cm at 10°C 42.9 dyn/cm at 20°C 24.4 dyn/cm at 180°C
Viscosity^[3]	6.023 mPa·s at 12°C 4.467 mPa·s at 20°C 2.92 mPa·s at 22°C 1.555 mPa·s at 60°C

Thermodynamic properties

Phase behavior
Triple point	267.13 K (–6.02 °C), ? Pa
Critical point	698.8 K (425.7 °C), 4890 kPa
Std enthalpy change of fusion, Δ_fusH^o	10.54 kJ/mol
Std entropy change of fusion, Δ_fusS^o	39.57 J/(mol·K) at –6.3°C
Std enthalpy change of vaporization, Δ_vapH^o	55.83 kJ/mol at 25°C 42.44 kJ/mol at 184.1°C
Std entropy change of vaporization, Δ_vapS^o	? J/(mol·K)
Solid properties
Std enthalpy change of formation, Δ_fH^o_solid	? kJ/mol
Standard molar entropy, S^o_solid	? J/(mol K)
Heat capacity, c_p	? J/(mol K)
Liquid properties
Std enthalpy change of formation, Δ_fH^o_liquid	31 kJ/mol
Standard molar entropy, S^o_liquid	191. J/(mol K)
Enthalpy of combustion, Δ_cH^o_liquid	–3393 kJ/mol
Heat capacity, c_p	193.7 J/(mol K) at 25°C
Gas properties
Std enthalpy change of formation, Δ_fH^o_gas	87 kJ/mol
Standard molar entropy, S^o_gas	? J/(mol K)
Heat capacity,^[4] c_p	148.7 J/(mol K) at 25°C
van der Waals' constants^[5]	a = 2685 L² kPa/mol² b = 0.1369 liter per mole

Vapor pressure of liquid

P in mm Hg		1	10	40	100	400	760	1520	3800	7600	15200	30400	45600
T in °C		34.8	69.4	96.7	119.9	161.9	184.4	212.8	254.8	292.7	342.0	400.0	—

Table data obtained from CRC Handbook of Chemistry and Physics 44th ed.

Distillation data

Spectral data

UV-Vis

λ_max

? nm

Extinction coefficient, ε

Major absorption bands^[7]

Wave number	transmittance
(liquid film)
3663 cm⁻¹	77%
3429 cm⁻¹	32%
3354 cm⁻¹	20%
3214 cm⁻¹	44%
3088 cm⁻¹	62%
3072 cm⁻¹	55%
3037 cm⁻¹	38%
3010 cm⁻¹	67%
2930 cm⁻¹	81%
2904 cm⁻¹	79%
2640 cm⁻¹	79%
2627 cm⁻¹	81%
1929 cm⁻¹	77%
1839 cm⁻¹	79%
1705 cm⁻¹	77%
1621 cm⁻¹	7%
1601 cm⁻¹	5%
1557 cm⁻¹	70%
1525 cm⁻¹	66%
1496 cm⁻¹	4%
1467 cm⁻¹	34%
1332 cm⁻¹	74%
1312 cm⁻¹	57%
1277 cm⁻¹	25%
1176 cm⁻¹	32%
1154 cm⁻¹	68%
1053 cm⁻¹	77%
1028 cm⁻¹	64%
996 cm⁻¹	60%
881 cm⁻¹	53%
754 cm⁻¹	8%
693 cm⁻¹	10%
620 cm⁻¹	47%
529 cm⁻¹	50%
504 cm⁻¹	18%

NMR

Proton NMR

Carbon-13 NMR

Other NMR data

Masses of
main fragments

UV Absorbance Spectroscopy of Aniline

Aniline is a benzenoid compound. The NH₂ group attached to the benzene ring means that there is a lone pair of electrons that can enter into conjugation with the benzene ring resulting in delocalization in the aniline.

Aniline absorbs in the K (220 - 250 nm) and the B (250 - 290 nm) bands exhibited by benzenoid compounds. The K and B bands arise from π to π* transitions as a result of the a group containing multiple bond being attached to the benzene ring. When dissolved in ethanol, λ_max for aniline is 230 nm, but in dilute aqueous acid λ_max is 203 nm. In the latter case the anilinium cation is formed and the lone pair is no longer available for conjugation with the benzene ring. Consequently, the absorption of the molecule shifts to the lower λ_max value and behaves like benzene.

Regulatory data

Regulatory data
Flash point	70°C
RTECS	?
Autoignition temperature	615°C

References

^ Lange's Handbook of Chemistry, 10th ed. pp 1234-1237
^ Lange's Handbook of Chemistry, 10th ed. pp 1661-1663
^ Lange's Handbook of Chemistry, 10th ed. pp 1669-1674
^ ^a ^b Pure Component Properties (Queriable database). Chemical Engineering Research Information Center. Retrieved on 28 May 2007.
^ Lange's Handbook of Chemistry, 10th ed, pp 1522-1524
^ ^a ^b Binary Vapor-Liquid Equilibrium Data (Queriable database). Chemical Engineering Research Information Center. Retrieved on 6 June 2007.
^ [http://www.aist.go.jp/RIODB/SDBS/cgi-bin/cre_index.cgi Spectral Database for Organic Compounds] (Queriable database). Advanced Industrial Science and Technology. Retrieved on 9 June 2007.

NIST Standard Reference Database.

Finar, I.L. (1974); Organic Chemistry Vol.2 - Stereochemistry and the chemistry of natural products 5th. Ed. Longman

Except where noted otherwise, data relate to standard ambient temperature and pressure.

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Category: Chemical data pages

This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Aniline_(data_page)". A list of authors is available in Wikipedia.